Liquid Solution - Physical Chemistry - Chemistry Previous Year Questions

At 300 K , the vapour pressure of toluene and benzene are 3.63 kPa and 9.7 kPa respectively. What is the composition of vapour in equilibrium with the solution containing 0.4 mole fraction of toluene?

(Assume the solution is ideal)

The osmotic pressure (in atm) of an aqueous solution containing 0.01 mol of NaCl (degree of dissociation 0.94 ) and 0.03 mol of glucose in 500 mL at $27^{\circ} \mathrm{C}$ is $\left(R=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)$

Observe the following statements

Statement I : The boiling point of 0.1 M urea solution is less than that of 0.1 M KCl solution.

Statement II : Elevation of boiling point is inversely proportional to molar mass of solute.

The correct answer is

Which of the following solution has highest amount of solute?

Two liquids ' $A$ ' and ' $B$ ' form an ideal solution. At 300 K , the vapour pressure of a solution containing 1 mole of ' $A$ ' and 3 moles of ' $B$ ' is 550 mm Hg . At the same temperature, if one more mole of ' $B$ ' is added to the solution, the vapour pressure of solution increases to 560 mm Hg . Then the ratio of vapour pressures of $A$ and $B$ in their pure state is

Observe the following data given in the table ( $K_H=$ Henry's law constant)

$$\begin{aligned} &\begin{array}{ccccc} \hline \text { Gas } & \mathrm{CO}_2 & \mathrm{Ar} & \mathrm{HCHO} & \mathrm{CH}_4 \\ \hline\left(\boldsymbol{K}_{\mathrm{H}} \text { bar at } \mathbf{2 9 8 ~ K}\right) & 1.67 & 40.3 & 1.83 \times 10^{-5} & 0.413 \\ \hline \end{array}\\ &\text { The correct order of their solubility in water is } \end{aligned}$$

Which one of the following mixtures can be separated by steam distillation technique?

1 mL of " $x$ volume" $\mathrm{H}_2 \mathrm{O}_2$ solution on heating gives 20 mL of oxygen gas at STP. The $(w / v) \%$ corresponding to " $x$ volume" of $\mathrm{H}_2 \mathrm{O}_2$ is

In a mixture of liquids $A$ and $B$, if the mole fractions of component $A$ in vapour phase and liquid mixture are $x_1$ and $x_2$ respectively, then the total vapour pressure of liquid mixture is

(Where $p_{\mathrm{A}}^0$ and $p_{\mathrm{B}}^0$ are the vapour pressure of pure $A$ and $B$ )