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Practice Coordination Compounds - Inorganic Chemistry - Chemistry previous year questions organised from real papers, with year-wise coverage and clear topic navigation.
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| Paper | Year / session | Questions in this view | Open |
|---|---|---|---|
| COMEDK 2025 AFTERNOON SHIFT | 2025 | 4 | View paper |
| COMEDK 2025 EVENING SHIFT | 2025 | 3 | View paper |
| COMEDK 2025 Morning Shift | 2025 | 4 | View paper |
| COMEDK 2024 AFTERNOON SHIFT | 2024 | 3 | View paper |
| COMEDK 2024 EVENING SHIFT | 2024 | 4 | View paper |
| COMEDK 2024 MORNING SHIFT | 2024 | 3 | View paper |
| COMEDK 2023 EVENING SHIFT | 2023 | 4 | View paper |
| COMEDK 2023 Morning Shift | 2023 | 6 | View paper |
| COMEDK 2022 | 2022 | 2 | View paper |
| COMEDK 2021 | 2021 | 2 | View paper |
| COMEDK 2020 | 2020 | 4 | View paper |
Practice every matching question in batches of 20, with every available option.
IUPAC name of Na\(_3\)[Co(NO\(_2\))\(_6\)] is
Which complex cannot ionise in solution?
The number of unidentate ligands in the complex ion is called
The oxidation state of iron in K\(_4\)[Fe(CN)\(_6\)] is,
Which type of ligand is EDTA?
The correct IUPAC name of the coordination compound K\(_3\)[Fe(CN)\(_5\)NO] is
The oxidation state of nickel in [Ni(CO\(_4\))] is
The complex which does not show optical isomerism is
Identify the correct IUPAC name of \([\mathrm{CoCl}_2(\mathrm{NO}_2)(\mathrm{NH}_3)_3]\)
Which one of the following is an incorrect statement pertaining to the properties of Coordination compounds?
Which one of the following Coordination entities exhibits Facial and Meridional isomerism?
Match the Coordination compounds given in Column I with their characteristic features listed in Column II.
| S.No. | Coordination compounds | S.No. | Characteristic features |
|---|---|---|---|
| W | $$ \[\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_3\] $$ |
P | $$ \[\text { Oxidation state }=+3 \text { Configuration }=\mathrm{d}^5 \quad \mu=5.92 \mathrm{BM}\] $$ |
| X | $$ \[\mathrm{K}_4\left[\mathrm{Mn}(\mathrm{CN})_6\right.\] $$ |
Q | $$ \[\text { Oxidation state }=+3 \text { Configuration }=\mathrm{d}^3 \quad \mu=3.87 \mathrm{BM}\] $$ |
| Y | $$ \[\left[\mathrm{CrCl}_3(\mathrm{py})_3\right]\] $$ |
R | $$ \[\text { Oxidation state }=+3 \text { Configuration }=d^6 \quad \mu=0 \mathrm{BM}\] $$ |
| Z | $$ \[\mathrm{Cs}\left[\mathrm{FeCl}_4\right]\] $$ |
S | $$ \[\text { Oxidation state }=+2 \text { Configuration }=\mathrm{d}^5 \quad \mu=1.732 \mathrm{BM}\] $$ |
On the basis of crystal field theory, electronic configuration of a low spin \(\mathrm{d}^4\) complex is:
The molar conductivity of the complex \(\mathrm{CoCl}_3 \cdot 4 \mathrm{NH}_3 \cdot 2 \mathrm{H}_2 \mathrm{O}\) is found to be the same as that of a \(1: 3\) electrolyte. The structural formula of the compound is :
The type of hybridisation and the spin only magnetic moment for the complex \([\mathrm{Ni}(\mathrm{CO})_4]\) are respectively:
Which of the following 2 compounds exhibit both Geometrical and Structural isomerism?
$$\begin{aligned} & \mathrm{A}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{NO}_2 \\ & \mathrm{~B}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right) \mathrm{Br}\right] \mathrm{SO}_4 \\ & \mathrm{C}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] \\ & \mathrm{D}=\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3 \end{aligned}$$
Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II
| No. | Complex ions | No. | Number of unpaired electrons |
|---|---|---|---|
| (A) | $$ \[\left[\mathrm{Fe} \mathrm{F}_6\right]^{3-}\] $$ |
(P) | 0 |
| (B) | $$ \[\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\] $$ |
(P) | 1 |
| (C) | $$ \[\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\] $$ |
(R) | 5 |
| (D) | $$ \[\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}\] $$ |
(S) | 4 |
Given below are 4 statements. Two of these are correct statements. Identify them.
A. \(\mathrm{Co}^{2+}\) is easily oxidised to \(\mathrm{Co}^{3+}\) in the presence of a strong ligand like \(\mathrm{CN}^{-}\)
B. \([\mathrm{Fe}(\mathrm{CN})_6]^{4-}\) is an octahedral complex ion which is paramagnetic in nature.
C. Removal of \(\mathrm{H}_2 \mathrm{O}\) molecules from \([\mathrm{Ti}(\mathrm{H}_2 \mathrm{O})_6] \mathrm{Cl}_3\) on strong heating converts it to a colourless compound.
D. Crystal Field splitting in Octahedral and Tetrahedral complexes is given by the equation \(\Delta_0=4 / 9 \Delta_t\)
Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.
| No. | Complexion | No. | d orbital configuration of central metal ion. |
|---|---|---|---|
| (A) | $$ \[\left[M n(C N)_6\right]^{4-}\] $$ |
(P) | $$ e_g^2 t_{2 g}^3 $$ |
| (B) | $$ \[\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\] $$ |
(Q) | $$ t_{2 g}^4 e_g^2 $$ |
| (C) | $$ \[\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\] $$ |
(R) | $$ t_{2 g}^5 $$ |
| (D) | $$ \[\left[\mathrm{MnCl}_4\right]^{2-}\] $$ |
(S) | $$ t_{2 g}^5 e_g^2 $$ |
Choose the incorrect statement from the following.
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