COMEDK 2024 EVENING SHIFT

Arrange the following redox couples in the increasing order of their reducing strength:

$$\begin{array}{ll} {[\mathrm{A}]=\mathrm{Cu} / \mathrm{Cu}^{2+}} & \mathrm{E}^0=-0.34 \mathrm{~V} \\ {[\mathrm{~B}]=\mathrm{Ag} / \mathrm{Ag}^{+}} & \mathrm{E}^0=-0.8 \mathrm{~V} \\ {[\mathrm{C}]=\mathrm{Ca} / \mathrm{Ca}^{2+}} & \mathrm{E}^0=+2.87 \mathrm{~V} \\ {[\mathrm{D}]=\mathrm{Cr} / \mathrm{Cr}^{3+}} & \mathrm{E}^0=+0.74 \mathrm{~V} \end{array}$$

What mass of Silver chloride, in grams, gets precipitated when $$150 \mathrm{~ml}$$ of $$32 \%$$ solution of Silver nitrate is reacted with $$150 \mathrm{ml}$$ of $$11 \%$$ Sodium chloride solution? Atomic mass in $$\mathrm{g} / \mathrm{mol}: \mathrm{Ag}=108, \mathrm{Na}=23, \mathrm{Cl}=35.5, \mathrm{~N}=14, \mathrm{O}=16$$

What is the quantity of charge, in Faraday units, required for the reduction of 3.5 moles of $$\mathrm{Cr}_2 \mathrm{O} 7^{2-}$$ in acid medium?

Four resistors, each of resistance R, are connected as shown in the figure below.

Arrange the following compounds in the increasing order of their reactivity when each of them is reacted with chloroethane / anhydrous AlCl$$_3$$.

Two finite sets have '$$m$$' and '$$n$$' number of elements respectively. The total number of subsets of the first set is 112 more than the total number of subsets of the second set. Then the values of $$\mathrm{m}$$ and $$\mathrm{n}$$ are respectively.

A cricketer of height $$2.5 \mathrm{~m}$$ throws a ball at an angle of $$30^{\circ}$$ with the horizontal such that it is received by another cricketer of same height standing at a distance of $$50 \mathrm{~m}$$ from the first one. The maximum height attained by the ball is ($$\tan 30^{\circ}=0.577$$)

The dimension $$[\mathrm{ML}^{-1} \mathrm{~T}^{-2}]$$ is the physical quantity of

The mean of five observations is 4 and their variance is 5.2 . If three of these observations are 1, 2 and 6, then the other two observations are

A body initially at rest undergoes rectilinear motion. The forcetime (F-t) graph for the motion of the body is given below. Find the linear momentum gained by the body in $$2 \mathrm{~s}$$.

A solid cylinder of mass $$2 \mathrm{~kg}$$ and radius $$0.2 \mathrm{~m}$$ is rotating about its own axis without friction with angular velocity $$5 \mathrm{~rad} \mathrm{s}^{-1}$$. A particle of mass $$1 \mathrm{~kg}$$ moving with a velocity of $$5 \mathrm{~ms}^{-1}$$ strikes the cylinder and sticks to it as shown in figure.

The angular velocity of the system after the particle sticks to it will be

A scooter moves with a speed of $$7 \mathrm{~ms}^{-1}$$, on a straight road and is stopped by applying the brakes. Before stopping, the scooter travels $$10 \mathrm{~m}$$. If the weight of the scooter is $$\mathrm{W}$$, then the total resistance to the motion of the scooter will be

A ball is moving in a circular path of radius $$5 \mathrm{~m}$$. If tangential acceleration at any instant is $$10 \mathrm{~ms}^{-2}$$ and the net acceleration makes an angle of $$30^{\circ}$$ with the centripetal acceleration, then, the instantaneous speed is

Joule second is the unit of

When water falls from a height of $$80 \mathrm{~m}$$ at the rate of $$20 \mathrm{~kg} \mathrm{~s}^{-1}$$ to operate a turbine the losses due to frictional force are $$20 \%$$ of input energy. How much power is generated by the turbine?

Action and reaction can never balance out because

The temperature of a wire is doubled. The Young's modulus of elasticity

The coefficient of volume expansion of glycerine is $$49 \times 10^{-5} \mathrm{~K}^{-1}$$. The percentage change in its density for a $$50^{\circ} \mathrm{C}$$ rise in temperature is

What is the relation obeyed by the angles of contact $$\theta_1, \theta_2$$ and $$\theta_3$$ of 3 liquids of different densities $$P_1, P_2$$ and $$P_3$$ respectively $$(\mathrm{P}_1 < \mathrm{P}_2 < \mathrm{P}_3$$) when they rise to the same capillary height in 3 identical capillaries and having nearly same surface tension $$\mathrm{T}$$ ?

Internal energy of $$\mathrm{n}_1$$ moles of hydrogen at temperature T is equal to internal energy of $$\mathrm{m}_2$$ moles of helium at temperature 2T. The ratio $$\frac{n_1}{n_2}$$ is

A cylinder of fixed capacity 44.81 contains hydrogen gas at STP. What is the amount of heat needed to raise the temperature of the gas in the cylinder by $$20^{\circ} \mathrm{C}$$ ? ($$R=8.31 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$$)

The latent heat of vaporisation of water is $$2240 \mathrm{~J}$$. If the work done in the process of vaporisation of $$1 \mathrm{~g}$$ is $$168 \mathrm{~J}$$, the increase in internal energy is

A monochromatic light of wavelength $$800 \mathrm{~nm}$$ is incident normally on a single slit of width $$0.020 \mathrm{~mm}$$ to produce a diffraction pattern on a screen placed $$1 \mathrm{~m}$$ away. Estimate the number of fringes obtained in Young's double slit experiment with slit separation $$0.20 \mathrm{~mm}$$, which can be accommodated within the range of total angular spread of the central maximum due to single slit.

The number of possible natural oscillations of air column in a pipe closed at one end of length $$85 \mathrm{~cm}$$ whose frequencies lie below $$1250 \mathrm{~Hz}$$ are (velocity of sound $$=340 \mathrm{~ms}^{-1}$$)

A satellite is revolving around the earth in a circular orbit with kinetic energy of $$1.69 \times 10^{10} \mathrm{~J}$$. The additional kinetic energy required for just escaping into the outer space is

The acceleration due to gravity at pole and equator can be related as

A body is executing SHM. When its displacements from the mean position are $$4 \mathrm{~cm}$$ and $$5 \mathrm{~cm}$$ it has velocity $$10 \mathrm{~cms}^{-1}$$ and $$8 \mathrm{~cms}^{-1}$$ respectively. Its periodic time $$\mathrm{t}$$ is

Two narrow parallel slits illuminated by a coherent monochromatic light produces an interference pattern on a screen placed at a distance $$\mathrm{D}$$ from the slits. The separation between the dark lines of the interference pattern can be increased by

A telescope has an objective of focal length $$60 \mathrm{~cm}$$ and eyepiece of focal length $$5 \mathrm{~cm}$$. The telescope is focussed for least distance of distinct vision $$300 \mathrm{~cm}$$ away from the object. The magnification produced by the telescope at least distance of distinct vision is

When a biconvex lens of glass of refractive index 1.5 is dipped in a liquid, it acts like a plane sheet of paper. This means the refractive index of the liquid is

In Young's double slit experiment light of wavelength $$500 \mathrm{~nm}$$ is used to form interference pattern. A uniform glass plate of refractive index 1.5 and thickness $$0.1 \mathrm{~mm}$$ is introduced in the path of one of the interfering beams. The number of fringes that will shift due to this is

Figure below shows a lens of refractive index, $$\mu=1.4$$. $$C_1$$ and $$C_2$$ are the centres of curvature of the two faces of the lens of radii of curvature $$4 \mathrm{~cm}$$ and $$8 \mathrm{~cm}$$ respectively.

The lens behaves as a

Incident light of wavelength $$\lambda=800 \mathrm{~nm}$$ produces a diffraction pattern on a screen $$1.5 \mathrm{~m}$$ away when it passes through a single slit of width $$0.5 \mathrm{~mm}$$. The distance between the first dark fringes on either side of the central bright fringe is

A hollow prism is filled with water and placed in air. It will deviate the incident rays

A neutral water molecule is placed in an electric field $$E=2.5 \times 10^4 \mathrm{NC}^{-1}$$. The work done to rotate it by $$180^{\circ}$$ is $$5 \times 10^{-25} \mathrm{~J}$$. Find the approximate separation of centre of charges.

The resistance of a $$10 \mathrm{~m}$$ long wire is $$10 \Omega$$. Its length is increased by $$25 \%$$ by stretching the wire uniformly. The new resistance is

Two point charges $$\mathrm{M}$$ and $$\mathrm{N}$$ having charges $$+q$$ and $$-q$$ respectively are placed at a distance apart. Force acting between them is $$\mathrm{F}$$. If $$30 \%$$ of charge of $$\mathrm{N}$$ is transferred to $$\mathrm{M}$$, then the force between the charges becomes:

Three bulbs of $$40 \mathrm{~W}, 60 \mathrm{~W}$$, and $$100 \mathrm{~W}$$ are arranged in series with a $$220 \mathrm{~V}$$ source. The maximum light is obtained from

Three point charges are located on a circular arc at $$\mathrm{A}, \mathrm{B}$$ and $$\mathrm{C}$$ as shown in the figure below. The total electric field at the centre of the $$\operatorname{arc}(\mathrm{C})$$ is

If 216 drops of the same size are charged at $$200 \mathrm{~V}$$ each and they combine to form a bigger drop, the potential of the bigger drop will be

A voltmeter of resistance $$1000 \Omega .0 .5 \mathrm{~V} /$$ div is to be converted into a voltmeter to make it to read $$=1 \mathrm{~V} / \mathrm{div}$$. The value of high resistance to be connected in series with it is

A parallel plate capacitor having a dielectric constant 5 and dielectric strength $$10^6 \mathrm{~V} \mathrm{~m}^{-1}$$ is to be designed with voltage rating of $$2 \mathrm{~kV}$$. The field should never exceed $$10 \%$$ of its dielectric strength. To have the capacitance of $$60 \mathrm{~pF}$$ the minimum area of the plates should be

A wire of length $$2 \mathrm{~m}$$ carries a current of $$1 \mathrm{~A}$$ along the $$\mathrm{x}$$ axis. A magnetic field $$B=B_0(i+j+k)$$ tesla exists in space. The magnitude of magnetic force on the wire is

The figure shows a network of five capacitors connected to a 20 V battery. Calculate the charge acquired by each 10 $$\mu$$F capacitor.

Figure below shows a network of resistors, cells, and a capacitor at steady state.

What is the current through the resistance 4 $$\Omega$$ ?

A negative charge particle is moving upward in a magnetic field which is towards north. The particle is deflected towards

For a paramagnetic material, the dependence of the magnetic susceptibility $$\chi$$ on the absolute temperature is given as

A bar magnet is held perpendicular to a uniform field. If the couple acting on the magnet is to be halved, by rotating it, the angle by which it is to be rotated is

A current I flows in an infinitely long wire with cross section in the form of semi-circular ring of radius $$1 \mathrm{~m}$$. The magnitude of the magnetic induction along its axis is

A transformer of $$100 \%$$ efficiency has 200 turns in the primary and 40000 turns in the secondary. It is connected to a $$220 \mathrm{~V}$$ main supply and secondary feeds to a $$100 \mathrm{~K} \Omega$$ resistance. The potential difference per turn is

A conducting circular loop is placed in a uniform magnetic field $$\mathrm{B}=0.125 \mathrm{~T}$$ with its plane perpendicular to the loop. If the radius of the loop is made to shrink at a constant rate of $$2 \mathrm{~mm} \mathrm{~s}^{-1}$$, then the induced emf when the radius is $$4 \mathrm{~cm}$$ is

The current in a coil changes steadily from $$3 \mathrm{~A}$$ to $$5 \mathrm{~A}$$ in $$0.2 \mathrm{~s}$$ when an emf of $$2 \mu \mathrm{V}$$ is induced in it. The self-inductance of the coil is

In the $$\mathrm{A} . \mathrm{C}$$. circuit given below, voltmeters $$\mathrm{V}_1$$ and $$\mathrm{V}_2$$ read $$100 \mathrm{~V}$$ each. Find the reading of the voltmeter $$\mathrm{V}_3$$ and the ammeter $$\mathrm{A}$$.

The magnetic flux linked with a coil is given by the equation: $$\phi=8 t^2+t+10$$. The e.m.f. induced in the coil in the $$3^{\text {rd }}$$ second will be

Column - I lists the waves of the electromagnetic spectrum. Column - II gives approximate frequency range of these waves. Match Column - I and Column - II and choose the correct match from the given choices.

The conductivity of a semiconductor increases with increase in temperature because

A) number density of free current carriers increases

B) relaxation time increases

C) both number density of carriers and relaxation time increase

D) number density of current carriers increases, relaxation time decreases but effect of decrease in relaxation time is much less than increase in number density

When an A.C. source is connected to a inductive circuit,

The output of the given circuit is

A. Negatively rectified half wave

B. Positively rectified half wave

C. Negatively rectified full wave

D. Zero all times

The binding energy per nucleon for $$\mathrm{C}^{12}$$ is $$7.68 \mathrm{~MeV}$$ and that for $$\mathrm{C}^{13}$$ is $$7.47 \mathrm{~MeV}$$. The energy required to remove a neutron from $$\mathrm{C}^{13}$$ is

An electron has a mass of $$9.1 \times 10^{-31} \mathrm{~kg}$$. It revolves round the nucleus in a circular orbit of radius $$0.529 \times 10^{-10} \mathrm{~m}$$ at a speed of $$2.2 \times 10^6 \mathrm{~ms}^{-1}$$. The magnitude of its angular momentum is

If an electron in a hydrogen atom jumps from the third orbit to the second orbit, it emits a photon of wavelength $$\lambda$$. When it jumps from the second to the first orbit, the corresponding wavelength of the photon will be

The distance of closest approach when an alpha particle of kinetic energy $$6.5 \mathrm{~MeV}$$ strikes a nucleus of atomic number 50 is

The following are the graphs of potential barrier versus width of the depletion region for a p-n junction diode.

Which of the following is correct?

$$ \text { If the nuclear radius of }{ }^{27} \mathrm{Al} \text { is } 3.6 \text { fermi, the nuclear radius of }{ }^{125} \mathrm{Fe} \text { is } $$

What is the wave number (Units $$\mathrm{cm}^{-1}$$) of the longest wave length transition in the Balmer series of Hydrogen spectrum? $$Z=1 \text { for } H$$

Sulphuric acid used in Lead Storage battery has a concentration of $$4.5 \mathrm{~M}$$ and a density of $$1.28 \mathrm{~g} / \mathrm{~ml}$$. The molality of the acid is __________.

A photon emitted during the de-excitation of electron from a state $$\mathrm{n}$$ to the second excited state in a hydrogen atom, irradiates a metallic electrode of work function $$0.5 \mathrm{~eV}$$, in a photocell, with a stopping voltage of $$0.47 \mathrm{~V}$$. Obtain the value of quantum number of the state '$$n$$'.

The Enthalpy of combustion of $$\mathrm{C}_6 \mathrm{H}_5 \mathrm{COOH}(\mathrm{s})$$ at $$25^{\circ} \mathrm{c}$$ and 1.0 atm pressure is $$-2546 \mathrm{~kJ} / \mathrm{mol}$$. What is the Internal energy change for this reaction?

A particle of mass $$2 \mathrm{mg}$$ has the same wavelength as a neutron moving with a velocity of $$3 \times 10^5 \mathrm{~ms}^{-1}$$. The velocity of the particle is (mass of neutron is $$1.67 \times 10^{-27} \mathrm{Kg}$$)

A solute $$\mathrm{X}$$ is found to exist as a dimer in water. A 4 molal solution of $$\mathrm{X}$$ shows a boiling point of $$101.04^{\circ} \mathrm{C}$$. What is the percentage association of $$\mathrm{X}$$ ? ($$\mathrm{K}_{\mathrm{b}}$$ for water $$=0.52 \mathrm{~K} / \mathrm{m}$$).

At $$700 \mathrm{~K}$$, the Equilibrium constant value for the formation of $$\mathrm{HI}$$ from $$\mathrm{H}_2$$ and $$\mathrm{I}_2$$ is 49.0 . 0.7 mole of $$\mathrm{HI}(\mathrm{g})$$ is present at equilibrium. What will be the concentrations of $$\mathrm{H}_2$$ and $$\mathrm{I}_2$$ gases if we initially started with $$\mathrm{HI}(\mathrm{g})$$ and allowed the reaction to reach equilibrium at the same temperature?

Given :

$$ \begin{gathered} \Delta \mathrm{H}^0 \mathrm{f}_{\text {of }} \mathrm{CO}_2(\mathrm{~g})=-393.5 \mathrm{~kJ} / \mathrm{mol} \\ \Delta \mathrm{H}^0{ }_{\mathrm{f}} \text { of } \mathrm{H}_2 \mathrm{O}(\mathrm{l})=-286 \mathrm{~kJ} / \mathrm{mol} \\ \Delta \mathrm{H}^0{ }_{\mathrm{f}} \text { of } \mathrm{C}_3 \mathrm{H}_6(\mathrm{~g})=+20.6 \mathrm{~kJ} / \mathrm{mol} \end{gathered} $$

$$\Delta \mathrm{H}^0$$ isomerisation of Cyclopropane to Propene $$=-33 \mathrm{~kJ} / \mathrm{mol}$$

What is the standard enthalpy of combustion of Cyclopropane?

Study the graph between partial pressure and mole fraction of some gases and arrange the gases P, Q, R and S dissolved in H$$_2$$O, in the decreasing order of their K_H values.

5.0 moles of an Ideal gas at 3.0 atm pressure and $$27^{\circ} \mathrm{C}$$ is compressed isothermally to half its volume by application of an external pressure of $$3.5 \mathrm{~atm}$$. What is the amount of work done (in joules) on the gas? Given: $$1 \mathrm{~L} \mathrm{~atm}=101.3 \mathrm{~J}: \mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$

What volume of $$0.2 \mathrm{~M}$$ Acetic acid is to be added to $$100 \mathrm{ml}$$ of $$0.4 \mathrm{M}$$ Sodium acetate so that a Buffer solution of $$\mathrm{pH}$$ equal to 4.94 is obtained? $$(\mathrm{pK}_{\mathrm{a}}$$ of $$\mathrm{CH}_3 \mathrm{COOH}=4.76)$$

Given that the freezing point of benzene is $$5.48^{\circ} \mathrm{C}$$ and its $$\mathrm{K}_{\mathrm{f}}$$ value is $$5.12{ }^{\circ} \mathrm{C} / \mathrm{m}$$. What would be the freezing point of a solution of $$20 \mathrm{~g}$$ of propane in $$400 \mathrm{~g}$$ of benzene?

$$200 \mathrm{ml}$$ of an aqueous solution contains $$3.6 \mathrm{~g}$$ of Glucose and $$1.2 \mathrm{~g}$$ of Urea maintained at a temperature equal to $$27^{\circ} \mathrm{C}$$. What is the Osmotic pressure of the solution in atmosphere units?

$$\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$ : Molecular Formula: Glucose is $$\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6$$ and of Urea is $$\mathrm{NH}_2 \mathrm{CONH}_2$$

In the redox reaction between $$\mathrm{Cr}_2 \mathrm{O}_7^{2-} / \mathrm{H}^{+}$$ and sulphite ion, what is the number of moles of electrons involved in producing 3.0 moles of the oxidised product?

Identify the correct statement regarding corrosion of iron rod left exposed to atmosphere.

A current of 3.0A is passed through 750 ml of 0.45 M solution of CuSO$$_4$$ for 2 hours with a current efficiency of 90%. If the volume of the solution is assumed to remain constant, what would be the final molarity of CuSO$$_4$$ solution?

Given below are 2 statements: Assertion and Reason. Choose the correct option.

Assertion: When Molar conductivity for a strong electrolyte is plotted versus $$\sqrt{C}(\mathrm{~mol} / \mathrm{L})^{1 / 2}$$, a straight line is obtained with intercept equal to Molar conductivity at infinite dilution for the electrolyte and Slope equal to $$-\mathrm{A}$$. All electrolytes of a given type have the same $$\mathrm{A}$$ value.

Reason: At infinite dilution, strong electrolytes of the same type will have different number of ions due to incomplete dissociation.

For a given reaction, ,$$\mathrm{X}(\mathrm{g})+\mathrm{Y}(\mathrm{g} \rightarrow \mathrm{Z}(\mathrm{g})$$, the order of reaction with respect to $$\mathrm{X}$$ and $$\mathrm{Y}$$ are $$\mathrm{m}$$ and $$\mathrm{n}$$ respectively. If the concentration of $$\mathrm{X}$$ is tripled and that of $$\mathrm{Y}$$ is decreased to one third, what is the ratio between the new rate to the original rate of the reaction?

In the presence of a catalyst at a given temperature of $$27^{\circ} \mathrm{C}$$, the Activation energy of a specific reaction is reduced by $$100 \mathrm{~J} / \mathrm{mol}$$. What is the ratio between the rate constants for the catalysed $$(\mathrm{k}_2)$$ and uncatalysed $$(\mathrm{k}_1)$$ reactions?

For a reaction $$5 X+Y \rightarrow 3 Z$$, the rate of formation of $$Z$$ is $$2.4 \times 10^{-5} \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$$ Calculate the average rate of disappearance of $$\mathrm{X}$$.

The Activation energy for the reaction $$A \rightarrow B+C$$, at a temperature $$\mathrm{TK}$$ was $$0.04606 \mathrm{~RT} \mathrm{~J} / \mathrm{mol}$$. What is the ratio of Arrhenius factor to the Rate constant for this reaction?

Identify the pair of molecules in which one of them is a molecule with an odd electron and the other has an expanded octet.

The following data was recorded for the decomposition of XY compound at 750K

What is the order of reaction with respect to decomposition of XY?

An inorganic compound $$\mathrm{W}$$ undergoes the following reactions:

$$ \begin{gathered} W+\frac{\mathrm{Na}_2 \mathrm{CO}_3}{\mathrm{O}_2 / \text { heat }} \rightarrow X+\frac{\mathrm{H}^{+}}{} \rightarrow Y_{(s)} \\ Y(a q)+\mathrm{KCl}(\mathrm{aq}) \rightarrow Z_{(S)} \end{gathered} $$

Z appears in the form of orange crystals and is used as an oxidising agent in acid medium. Identify the compound W.

Which of the following two molecular species are Diamagnetic in nature?

$$[\mathrm{A}]=\mathrm{O}_2^{-} \quad[\mathrm{B}] .=\mathrm{N}_2^{+} \quad[\mathrm{C}]=\mathrm{C}_2 \quad[\mathrm{D}]=\mathrm{O}_2{ }^{2-}$$

Identify the correct statement from the following.

Choose the incorrect statement from the following:

A. Isoelectronic molecules/ions have the same bond order.

B. Dipole moment of $$\mathrm{NH}_3$$ is greater than that of $$\mathrm{NF}_3$$.

C. The Carbon in Methyl Carbocation is $$\mathrm{sp}^3$$ hybridised.

D. The stability of an ionic compound is measured in terms of its lattice enthalpy and not simply based on attaining Octet configuration.

With reference to Pauling's Electronegativity scale, which one of the following options shows the correct order of electronegativity values of elements?

The Lanthanoid ion which would form coloured compounds is -------------.

Atomic numbers: $$\mathrm{Yb}=70, \quad \mathrm{Lu}=71, \mathrm{Pr}=59, \quad \mathrm{La}=57$$

Which of the following 2 compounds exhibit both Geometrical and Structural isomerism?

$$\begin{aligned} & \mathrm{A}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{NO}_2 \\ & \mathrm{~B}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right) \mathrm{Br}\right] \mathrm{SO}_4 \\ & \mathrm{C}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] \\ & \mathrm{D}=\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3 \end{aligned}$$

Identify the product $$[\mathrm{C}]$$ formed at the end of the reaction below

1,1,2,2- Tetrabromopropane + 2 $$\mathrm{Zn}_{(\mathrm{S})}$$ / Ethanol $$\rightarrow$$ [B]

$$[\mathrm{B}]$$ + 2 moles of $$\mathrm{HBr} \rightarrow[\mathrm{C}]$$

Given below are 4 statements. Two of these are correct statements. Identify them.

A. $$\mathrm{Co}^{2+}$$ is easily oxidised to $$\mathrm{Co}^{3+}$$ in the presence of a strong ligand like $$\mathrm{CN}^{-}$$

B. $$[\mathrm{Fe}(\mathrm{CN})_6]^{4-}$$ is an octahedral complex ion which is paramagnetic in nature.

C. Removal of $$\mathrm{H}_2 \mathrm{O}$$ molecules from $$[\mathrm{Ti}(\mathrm{H}_2 \mathrm{O})_6] \mathrm{Cl}_3$$ on strong heating converts it to a colourless compound.

D. Crystal Field splitting in Octahedral and Tetrahedral complexes is given by the equation $$\Delta_0=4 / 9 \Delta_t$$

Identify the compound which is non-aromatic in nature.

Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II

Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.

Two statements, Assertion and Reason are given below. Choose the correct option.

Assertion: n-propyl tert-butyl ether can be readily prepared in the laboratory by Williamson's synthesis.

Reason: The reaction occurs by $$\mathrm{S}_{\mathrm{N}} 1$$ attack of Primary alkoxide on Tert-alkyl halide to give good yield of the product, n-propyl tert-butyl ether.

Match the names of reactions given in Column I with the appropriate reactions given in Column II.

Arrange the compounds $$\mathrm{A}, \mathrm{B}, \mathrm{C}$$ and $$\mathrm{D}$$ in the increasing order of their reactivity towards $$\mathrm{S_N}1$$ reaction.

$$ \begin{aligned} & \mathrm{A}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Cl} \\ & \mathrm{B}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl} \\ & \mathrm{C}=\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl} \\ & \mathrm{D}=\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{Cl} \end{aligned}$$

Identify the products C, D and F formed in the following sets of reactions.

4 statements are given below. Identify the incorrect statement

A. Phenol has lower $$\mathrm{pK}_{\mathrm{a}}$$ value than $$\mathrm{p}$$-cresol

B. 2-Chlorophenol is more acidic than phenol

C. Ortho and para nitrophenols can be separated by steam distillation since $$\mathrm{p}$$-Nitrophenol is more steam volatile than o-Nitrophenol

D. Phenol on reaction with $$\frac{\mathrm{Cr}_2 \mathrm{O}_7^{2-}}{\mathrm{H}^{+}}$$ yields a conjugated diketone

Identify the final product formed when Toluene undergoes a series of reactions with reagents given in the order:

(i) $$\mathrm{Cl}_2$$ / Sunlight

(ii) $$\mathrm{H}_2 \mathrm{O} / 373 \mathrm{~K}$$

(iii) Acetophenone / $$\mathrm{OH^-}$$ at $$293 \mathrm{~K}$$

Identify the end-product [D] formed when solution salicylate undergoes the following series of reactions

Given are the names of 4 compounds. Two of these compounds will not undergo Cannizzaro's reaction. Identify the two.

A. 2-Chlorobutanal

B. 2,2-Dimethylpropanal

C. Benzaldehyde

D. 2-Phenyl ethanol

Compounds $$\mathrm{A}$$ and $$\mathrm{B}$$, having the same molecular formula $$(\mathrm{C}_4 \mathrm{H}_8 \mathrm{O})$$, react separately with $$\mathrm{CH}_3 \mathrm{MgBr}$$, followed by reaction with dil. $$\mathrm{HCl}$$ to form compounds $$\mathrm{X}$$ and $$\mathrm{Y}$$ respectively. Compound $$\mathrm{Y}$$ undergoes acidic dehydration in presence of Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$ much more readily than $$\mathrm{X}$$. Compound $$\mathrm{Y}$$ also reacts with Lucas reagent, much more readily than $$\mathrm{X}$$, with appearance of turbidity. Identify $$\mathrm{X}$$ and $$\mathrm{Y}$$.

Which one of the following is the correct order of reagents to be used to convent [A] to [X] ?

$$ \text { Reagents: } \mathrm{PCC}, \mathrm{PCl}_5, \mathrm{LiAlH}_4, \frac{\mathrm{KCN}}{\mathrm{H}_3 \mathrm{O}^{+}} $$

Identify the final product formed when Benzamide undergoes the following reactions:

What is/are the product/s formed when Benzaldehyde and Ethanal react in presence of dil. $$\mathrm{NaOH}$$ followed by heating the intermediate product formed?

Identify the final product $$[\mathrm{D}]$$ formed when Benzyl alcohol undergoes the following series of reactions

$$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH}+\mathrm{SOCl}_2 \rightarrow[\mathrm{A}]+\mathrm{KCN} \rightarrow[\mathrm{B}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(partial hydrolysis) } \rightarrow[\mathrm{C}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(complete hydrolysis) } \rightarrow[\mathrm{D}]$$

One of the reactions A, B, C, D given below yields a product which will not answer Hinsberg's test when reacted with Benzene sulphonyl chloride. Identify the reaction.

A compound having molecular formula $$\mathrm{C}_4 \mathrm{H}_{11} \mathrm{N}$$, reacts with $$\mathrm{CHCl}_3$$ in alcoholic $$\mathrm{KOH}$$, on heating, to form a compound with a foul smell. Identify the optically active isomer of the compound which also shows the above reaction.

Match the Vitamins given in Column I with the diseases caused by their deficiency as given in Column II.

Given are 4 statements related to the chemical properties of Glucose.

Identify the two incorrect statements from the following.

A. It reacts with $$\mathrm{Br}_2$$ (aq) to form Saccharic acid.

B. Reacts with Acetic anhydride to form Glucose tetraacetate.

C. Reacts with Hydroxylamine to give Glucose oxime.

D. It reacts with ammoniacal $$\mathrm{AgNO}_3$$ to form ammonium salt of Gluconic acid with deposition of silver.

Two statements, Assertion and Reason are given. Choose the correct option from the following.

Assertion: In the secondary structure of RNA, double helix structure is formed.

Reason: In the double structure of RNA, two nucleic acid chains are wound about each other and held together by hydrogen bonds between pairs of bases

In the estimation of element $$\mathrm{X}$$ in an organic compound, $$0.8 \mathrm{~g}$$ of the compound containing $$\mathrm{X}$$ was heated with fuming $$\mathrm{HNO}_3$$ and the cooled product was treated with barium chloride. The mass of barium sulphate precipitated was $$1.2 \mathrm{~g}$$. What is the percentage of element $$\mathrm{X}$$ and what is the formula of the violet-coloured compound formed when Lassaigne's extract of the organic compound is treated with sodium nitroprusside?

$$ \text { If }(1-4 i)^3=a+i b \text { then the value of } \mathrm{a} \text { and } \mathrm{b} \text { is } $$

The shaded region in the Venn diagram represents

If two positive numbers are in the ratio $$3+2 \sqrt{2}: 3-2 \sqrt{2}$$, then the ratio between their A.M (arithmetic mean) and G.M (geometric mean) is

Which of the following relations on the set of real numbers $$\mathrm{R}$$ is an equivalence relation?

$$ \text { The solution set for the inequality } 13 x-5<15 x+4<7 x+12 ; x \in W \text { is } $$

Consider an infinite geometric series with first term '$$a$$' and common ratio '$$r$$'. If the sum of infinite geometric series is 4 and the second term is $$\frac{3}{4}$$ then

Suppose we have three cards identical in form except that both sides of the first card are coloured red, both sides of the second are coloured black, and one side of the third card is coloured red and the other side is coloured black. The three cards are mixed and a card is picked randomly. If the upper side of the chosen card is coloured red, what is the probability that the other side is coloured black.

While shuffling a pack of cards, 3 cards were accidently dropped, then find the probability that the missing cards belong to different suits?

The letters of the word "COCHIN" are permuted and all the permutations are arranged in alphabetical order as in an English dictionary. The number of words that appear before the word "COCHIN" is

For an examination a candidate has to select 7 questions from three different groups $$\mathrm{A}, \mathrm{B}$$ and C. The three groups contain 4, 5 and 6 questions respectively. In how many different ways can a candidate make his selection if he has to select atleast 2 questions from each group?

A number consists of three digits in geometric progression. The sum of the right hand and left hand digits exceeds twice the middle digit by 1 and the sum of left hand and middle digits is two third of the sum of the middle and right hand digits. Then the sum of digits of number is

A coin is tossed until a head appears or until the coin has been tossed three times. Given that 'head' does not appear on the first toss, what is the probability that the coin is tossed thrice?

In the expansion $$\left(\frac{1}{x}+x \sin x\right)^{10}, \quad$$ the co - efficient of $$6^{\text {th }}$$ term is equal to $$7 \frac{7}{8}$$, then the principal value of $$x$$ is

What is the probability of a randomly chosen 2 digit number being divisible by 3 ?

$$ \text { If } \hat{\imath}+\hat{\jmath}-\hat{k} \quad \&~ 2 \hat{\imath}-3 \hat{\jmath}+\hat{k} \text { are adjacent sides of a parallelogram, then length of its diagonals are } $$

Let $$\mathrm{A}$$ and $${B}$$ be two events such that $$P(A / B)=\frac{1}{2}$$ and $$P(B / A)=\frac{1}{3}$$ and $$P(A \cap B)=\frac{1}{6}$$ then, which one of the following is not true?

Find the value of '$$b$$' such that the scalar product of the vector $$\hat{\imath}+\hat{\jmath}+\hat{k}$$ with the unit vector parallel to the sum of the vectors $$2 \hat{\imath}+4 \hat{\jmath}-5 \hat{k}$$ and $$b \hat{\imath}+2 \hat{\jmath}+3 \hat{k}$$ is unity

The measure of the angle between the lines $$x=k+1, \quad y=2 k-1, \quad z=2 k+3, \quad k \in R \quad$$ and $$\quad \frac{x-1}{2}=\frac{y+1}{1}=\frac{z-1}{-2}$$ is

The co-ordinate of the foot of the perpendicular from $$P(1,8,4)$$ on the line joining $$R(0,-1,3)$$ and $$Q(2,-3,-1)$$ is

If the straight lines $$\frac{x-2}{1}=\frac{y-3}{1}=\frac{z-4}{-t}$$ and $$\frac{x-1}{t}=\frac{y-4}{2}=\frac{z-5}{1}$$ are intersecting then $$t$$ can have

If $$A=\left[\begin{array}{ccc}0 & x & 16 \\ x & 5 & 7 \\ 0 & 9 & x\end{array}\right]$$ is a singular matrix then $$x$$ is equal to

$$ \text { If } 3 A+4 B^t=\left(\begin{array}{ccc} 7 & -10 & 17 \\ 0 & 6 & 31 \end{array}\right) \text { and } 2 B-3 A^t=\left(\begin{array}{cc} -1 & 18 \\ 4 & -6 \\ -5 & -7 \end{array}\right) \text { then }(5 B)^t= $$

$$ \text { If } A=\left[\begin{array}{cc} 5 a & -b \\ 3 & 2 \end{array}\right] \text { and } A \operatorname{adj} A=A A^t \text {, then } 5 a+b \text { is equal to } $$

If the matrix $A$ is such that $$A\left(\begin{array}{cc}-1 & 2 \\ 3 & 1\end{array}\right)=\left(\begin{array}{cc}-4 & 1 \\ 7 & 7\end{array}\right)$$ then $$A$$ is equal to

$$ \text { If } \frac{\cos x}{\cos (x-2 y)}=\lambda \text { then } \tan (x-y) \tan y= $$

$$ \sqrt{2+\sqrt{2+\sqrt{2+2 \cos 8 \theta}}} \text { where } \theta \in\left[-\frac{\pi}{8}, \frac{\pi}{8}\right] \text { is equal to } $$

$$ \text { Value of } \cos 105^{\circ} \text { is } $$

The maximum value of $$P=500 x+400 y$$ for the given constraints $$x+y \leq 200, \quad x \geq 20, \quad y \geq 4 x, \quad y \geq 0$$ is

$$ \text { Evaluate: } \cot ^{-1}\left(-\frac{3}{\sqrt{3}}\right)-\sec ^{-1}\left(-\frac{2}{\sqrt{2}}\right)-\operatorname{cosec}^{-1}(-1)-\tan ^{-1}(1) $$

$$ \text { Evaluate: } \cos ^{-1}\left(\cos \frac{35 \pi}{18}\right)-\sin ^{-1}\left(\sin \frac{35 \pi}{18}\right) $$

$$ \text { The function } f(x)=\tan ^{-1}(\sin x+\cos x) \text { is an increasing function in } $$

The line joining two points $$A(2,0) B(3,1)$$ is rotated about $$A$$ in anticlockwise direction through an angle of $$15^{\circ}$$. If $$B$$ goes to $$C$$ in the new position, then the coordinates of $$C$$ is

$$ \text { The area of the region enclosed by the curve }\left\{(x, y): 4 x^2+25 y^2=100\right\} \text { is } $$

The area of the triangle whose vertices are $$(-2, a)(2,-6)$$ and $$(5,4)$$ is 35 sq units then the value of '$$\mathrm{a}$$' is

The points on the $$x$$-axis whose perpendicular distance from the line $$\frac{x}{3}+\frac{y}{4}=1$$ is 4 units are

The domain of the function $$y=\frac{1}{\log _{10}(3-x)}+\sqrt{x+7}$$ is

$$ \text { If } f(x)=\left\{\begin{array}{cc} x & , \quad 0 \leq x \leq 1 \\ 2 x-1 & , \quad x>1 \end{array}\right. \text { then } $$

In the parabola $$y^2=4 a x$$ the length of the latus rectum is 6 units and there is a chord passing through its vertex and the negative end of the latus rectum. Then the equation of the chord is

Let $$\alpha$$ and $$\beta$$ be the distinct roots of $$a x^2+b x+c=0$$, then $$\lim _\limits{x \rightarrow \alpha} \frac{1-\cos \left(a x^2+b x+c\right)}{(x-\alpha)^2}$$ is equal to

$$ \text { The value of } \lim _\limits{x \rightarrow 1} \frac{x^{15}-1}{x^{10}-1}= $$

The equation of the circle which touches the $$x$$-axis, passes through the point $$(1,1)$$ and whose centre lies on the line $$x+y=3$$ in the first quadrant is

$$ \text { If } y=\sin ^{-1}\left(\frac{5 x+12 \sqrt{1-x^2}}{13}\right) \text { then } \frac{d y}{d x} \text { equals } $$

What is the nature of the function $$f(x)=x^3-3 x^2+4 x$$ on real numbers?

$$ \text { If } y=\sqrt{\sin x+y} \text { then find } \frac{d y}{d x} \text { at } x=0, \quad y=1 $$

$$ \text { If } y=f(x), \quad p=\frac{d y}{d x} ; q=\frac{d^2 y}{d x^2} \text { then } \frac{d^2 x}{d y^2} \text { is equal to } $$

The turning point of the function $$y=\frac{a x-b}{(x-1)(x-4)}$$ at the point $$P(2,-1)$$ is

The side of a cube is equal to the diameter of a sphere. If the side and radius increase at the same rate then the ratio of the increase of their surface area is

$$ \text { The rate of change of the volume of a sphere with respect to its surface area } \mathrm{S} \text { is } $$

$$ \text { The value of } \int \frac{d x}{\sqrt{2 x-x^2}} \text { is } $$

$$ \int e^x\left[\frac{x^2+1}{(x+1)^2}\right] d x \quad \text { is equal to } $$

$$ \text { If } I_n=\int_\limits0^{\frac{\pi}{4}} \tan ^n x d x \text {, for } n \geq 2 \text {, then } I_n+I_{n-2}= $$

If $$a$$ is a real number such that $$\int_\limits0^a x d x \leq a+4$$ then

$$ \text { The value of the integral } \int_\limits{\frac{1}{3}}^1 \frac{\left(x-x^3\right)^{\frac{1}{3}}}{x^4} d x \text { is } $$

Given below are 4 reactions. Two of these reactions will give product which is an equimolar mixture of the d and 1 forms. Identify these 2 reactions.

[A] 2- Methylpropene + $$\mathrm{HI} \rightarrow$$ ---------

[B] But-1-ene + $$\mathrm{HBr} \rightarrow$$ -----------

[C] 3-Methylbut-1-ene + $$\mathrm{HI} \rightarrow$$ -----------

[D] 3- Phenylpropene + $$\mathrm{HBr}$$ (Peroxide) $$\rightarrow$$ -----------

$$ \text { If } \frac{d y}{d x}=y+3>0 \text { and } y(0)=2 \text { then } y(\log 2) \text { is equal to } $$

The sum of the order and degree of the differential equation $$\left(\frac{d^2 y}{d x^2}\right)^5+\frac{4\left(\frac{d^2 y}{d x^2}\right)^3}{\left(\frac{d^3 y}{d x^3}\right)}+\frac{d^3 y}{d x^3}=x^2-1$$ is

$$ \text { The general solution of the differential equation }(1+\tan y)(d x-d y)+2 x d y=0 \text { is } $$

The general solution of the differential equation $$x \frac{d y}{d x}=y+x \tan \left(\frac{y}{x}\right)$$ is

The area bounded by the curve $$y=\cos x, x=0$$ and $$x=\pi$$ is

A dry cell consists of a moist paste of $$\mathrm{NH}_4 \mathrm{Cl}$$ and $$\mathrm{ZnCl}_2$$ contained in a $$\mathrm{Zn}$$ casing which encloses a Carbon rod surrounded by black $$\mathrm{MnO}_2$$ paste. What is the role of $$\mathrm{ZnCl}_2$$ in it?

A Hydrocarbon [A] (molecular formula $$\mathrm{C}_3 \mathrm{H}_6$$) on reaction with $$\mathrm{Br}_2 / \mathrm{CCl}_4$$ gave [B]. When [B] is heated with 2 moles of alcoholic $$\mathrm{KOH}$$, it gave compound [C]. 3 moles of Compound [C] when passed through red hot Iron tube forms [D]. Identify [D].