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NCERT · Class 12 · Chemistry

Chapter 5: Coordination Compounds

Practice each question, then open the answer or worked solution.

In-text questions

11 questions
Q11Written answer

Calculate the overall complex dissociation equilibrium constant for the $\text{Cu(N}{{\text{H}}_{\text{3}}}\text{)}_{\text{4}}^{\text{2+}}$ ion, given that ${{\text{ }\!\!\beta\!\!\text{ }}_{\text{4}}}$ for this complex is $\text{2}\text{.1  }\!\!\times\!\!\text{  1}{{\text{0}}^{\text{13}}}$.

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Worked solution

Ans: We are given the overall stability constant (${{\text{ }\!\!\beta\!\!\text{ }}_{\text{4}}}$) = $\text{2}\text{.1  }\!\!\times\!\!\text{  1}{{\text{0}}^{\text{13}}}$.

The overall complex dissociation equilibrium constant is the reciprocal of the overall stability constant. This is given below:\[\text{Overall dissociation constant = }\frac{\text{1}}{{{\text{ }\!\!\beta\!\!\text{ }}_{\text{4}}}}\text{ = }\frac{\text{1}}{\text{2}\text{.1  }\!\!\times\!\!\text{  1}{{\text{0}}^{\text{13}}}}\text{ = 4}\text{.7  }\!\!\times\!\!\text{  1}{{\text{0}}^{\text{-14}}}\] 


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