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NCERT Exemplar · Class 12 · Chemistry

Chapter 7: The P-Block Elements

Practice each question, then open the answer or worked solution.

I. Multiple Choice Questions (Type-I)

27 questions
Q1Multiple choice

On addition of conc. H2SO4 to a chloride salt, colourless fumes are evolved but in case of an iodide salt, violet fumes come out. This is because

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q2Multiple choice

In qualitative analysis when H2S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO3, it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives _________.

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Correct option: B
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Worked solution

Option (ii) is the answer.

Q3Multiple choice

In a cyclotrimetaphosphoric acid molecule, how many single and double

bonds are present?

Solution;

Option (iii) is the answer.

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Worked solution

Solution coming soon.

Q4Multiple choice

Which of the following elements can be involved in pπ–dπ bonding?

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q5Multiple choice

Which of the following pairs of ions are isoelectronic and isostructural?

Option (i) is the answer.

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Solution coming soon.

Q6Multiple choice

Affinity for hydrogen decreases in the group from fluorine to iodine. Which of

the halogen acids should have the highest bond dissociation enthalpy?

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Correct option: A
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Worked solution

Option (i) is the answer.

Q7Multiple choice

Bond dissociation enthalpy of E—H (E = element) bonds are given below. Which

of the compounds will act as the strongest reducing agent?

Compound

∆diss (E—H)/kJ mol–1

NH3

389

PH3

322

AsH3

297

SbH3

255

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Correct option: D
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Worked solution

Option (iv) is the answer.

Q8Multiple choice

On heating with concentrated NaOH solution in an inert atmosphere of CO2, white phosphorus gives a gas. Which of the following statement is incorrect about the gas?

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q9Multiple choice

Which of the following acids forms three series of salts?

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q10Multiple choice

Strong reducing behaviour of H3PO2 is due to

Option (iii) is the answer.

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Worked solution

Solution coming soon.