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NCERT Exemplar · Class 11 · Chemistry

Chapter 4: Chemical Bonding and Molecular Structure

Practice each question, then open the answer or worked solution.

Questions

51 questions
Q1Multiple choice

Isostructural species are those which have the same shape and hybridisation.

Among the given species, identify the isostructural pairs.

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Correct option: B
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Worked solution

Option (ii) is the answer.

Q2Multiple choice

Polarity in a molecule and hence the dipole moment depends primarily on

electronegativity of the constituent atoms and shape of a molecule. Which of

Does the following have the highest dipole moment?

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q3Written answer

The types of hybrid orbitals of nitrogen in NO2+, NO3- and NH4+respectively are expected to be

(i) sp, sp3 and sp2

(ii) sp, sp2 and sp3

(iii) sp2, sp and sp3

(iv) sp2, sp3 and sp

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Worked solution

Option (ii) is the answer.

Q4Multiple choice

Hydrogen bonds are formed in many compounds e.g., H2O, HF, NH3. The boiling point of such compounds depends to a large extent on the strength of hydrogen bond and the number of hydrogen bonds. The correct decreasing order of the boiling points of the above compounds is :

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Correct option: B
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Worked solution

Option (ii) is the answer.

Q5Written answer

In PO43- ion, the formal charge on the oxygen atom of P–O bond is

(i) + 1

(ii) – 1

(iii) – 0.75

(iv) + 0.75

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Worked solution

Option (ii) is the answer.

Q6Written answer

In NO3-ion, the number of bond pairs and lone pairs of electrons on the nitrogen

atom is

(i) 2, 2

(ii) 3, 1

(iii) 1, 3

(iv) 4, 0

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Worked solution

Option (iv) is the answer.

Q7Multiple choice

Which of the following species has tetrahedral geometry?

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Correct option: A
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Worked solution

Option (i) is the answer.

Q8Written answer

Number of π bonds and σ bonds in the following structure is–

NCERT Exemplar Solutions of Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure-1

(i) 6, 19

(ii) 4, 20

(iii) 5, 19

(iv) 5, 20

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Worked solution

Option (iii) is the answer.

Q9Multiple choice

Which molecule/ion out of the following does not contain unpaired electrons?

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Correct option: C
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Worked solution

Option (iii) is the answer.

Q10Multiple choice

In which of the following molecules/ions all the bonds are not equal?

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Correct option: C
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Worked solution

Option (iii) is the answer.