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NCERT Exemplar · Class 11 · Chemistry

Chapter 3: Classification of Elements and Periodicity in Properties

Practice each question, then open the answer or worked solution.

Short Answer Questions

25 questions
Q34Written answer

p-Block elements form acidic, basic and amphoteric oxides. Explain each property by giving two examples and also write the reactions of these oxides with water.

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Worked solution

Ans: In the p block, some elements are metallic some elements are non-metallic while some elements are metalloids in nature.

The oxides of metals are basic in nature and that of oxides of nonmetals are acidic in nature.

Acidic oxide

SO2 + H2O $\to $H2SO3

Basic oxide

Tl2O + 2HCl $\to $ 2TlCl +H2O

Amphoteric oxide

Al2O3 + 6HCl $\to $ 2AlCl3 + 3H2O

Al2O3 +2 NaOH $\to $ 2NaAlO2 + H2O

Reaction with water

\[{{\text{B}}_{\text{2}}}{{\text{O}}_{\text{3}}}\text{3}{{\text{H}}_{\text{2}}}\text{O}\to 2{{\text{H}}_{\text{3}}}\text{B}{{\text{O}}_{\text{3}}}\]

\[{{\text{P}}_{\text{4}}}{{\text{O}}_{\text{11}}}\text{6}{{\text{H}}_{\text{2}}}\text{O}\to \text{4}{{\text{H}}_{\text{3}}}\text{P}{{\text{O}}_{4}}\]

\[\text{C}{{\text{l}}_{\text{2}}}{{\text{O}}_{\text{7}}}\text{+}{{\text{H}}_{\text{2}}}\text{O}\to \text{HCl}{{\text{O}}_{\text{4}}}\]


Q35Written answer

How would you explain the fact that the first ionisation enthalpy of sodium is lower than that of magnesium but its second ionisation enthalpy is higher than that of magnesium?

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Worked solution

Ans: The electronic configuration of Na is (Ne)3s1 while that of Mg is (Ne)3s2 as Mg possesses a fully filled 3s orbital thus its first ionisation enthalpy is higher than that of Na.

After losing one electron Na obtained the electronic configuration of Ne while Mg acquired the electronic configuration of Na thus the second ionisation energy of Na is higher than that of Mg.


Q36Written answer

What do you understand about exothermic reactions and endothermic reactions? Give one example of each type.

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Ans: Exothermic reaction- The reaction reaction in which heat is released.

For example- CaO + CO2 → CaCO3 + Heat

Endothermic reaction- The reaction in which heat is absorbed.

For example- 2NH3  + heat → N2 +3H2


Q37Written answer

Arrange the elements N, P, O and S in the order of- 

(i) increasing first ionisation enthalpy. 

(ii) increasing non metallic character. 

Give reason for the arrangement assigned.

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Worked solution

Ans: (i) S<P<O<N

The ionization enthalpy increases across the period and decreases down the group.

N possesses a half filled 2p orbital which provides it extra stability due to symmetry.

(ii)P<S<N<O

The non-metallic character increases across the period .


Q38Written answer

Explain the deviation in ionisation enthalpy of some elements from the general trend by using Fig. 3.2


seo images


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Worked solution

Ans: The deviation in the ionization enthalpy of some elements from the general trend can be explained by the points as given below:-

(i) The fully filled and half filled orbital provide extra stability due to the symmetry

(ii) The effective nuclear charge

(iii) The e--e- repulsion which lead to instability


Q39Written answer

Explain the following: 

(a) Electronegativity of elements increase on moving from left to right in the periodic table. 

(b) Ionisation enthalpy decrease in a group from top to bottom?

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Ans: As the effective nuclear charge increases and shielding effect decreases across the periods thus the electronegativity increass on moving from left  to right in the periodic table.


Ans: As the number of shells increases down the group thus its ionisation enthalpy decreases down the group.


Q40Written answer

How does the metallic and non metallic character vary on moving from left to right in a period?

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Ans: Metallic character- Tendency to lose electrons.

Non-Metallic character- Tendency to accept electrons.

Across the period the metallic character decreases whereas non-metallic character increases across the period.


Q41Written answer

The radius of Na+ cation is less than that of Na atom. Give reason.

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Worked solution

Ans: The radius of Na+ ion is smaller than that of Na is due to the following reasons:-

(i) The effective nuclear charge of Na+ increases

(ii) The disappearance of 3s orbital from its outermost shell electronic configuration


Q42Written answer

Among alkali metals which element do you expect to be least electronegative and why?

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Worked solution

Ans: The electronegativity of the alkali metals decreases down the group due to the increase of the shells thus Cs (Caesium) is the least electronegative metal in the alkali metals.


Matching Type
Q43Written answer

Match the correct atomic radius with the element.

Element

Atomic Radius (pm)

Be

74

C

88

O

111

B

77

N

66


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Worked solution

Ans:

Be

111

C

77

O

66

B

88

N

74