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NCERT Exemplar · Class 11 · Chemistry

Chapter 14: Environmental Chemistry

Practice each question, then open the answer or worked solution.

Long Answer Questions

5 questions
Q46Written answer

How can you apply green chemistry for the following: 

(i) to control photochemical smog. 

(ii) to avoid use of halogenated solvents in dry cleaning and that of chlorine in bleaching. 

(iii) to reduce use of synthetic detergents. 

(iv) to reduce the consumption of petrol and diesel. 

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Worked solution

Ans: Many techniques are used to control or reduce the formation of photochemical smog. 

(1) If we control the primary precursors of photochemical smog, such as nitrogen dioxide and hydrocarbons, the secondary precursors such as ozone and PAN of the photochemical smog will automatically get reduced.

(2) Mostly catalytic converters are used in automobiles to prevent the release of nitrogen oxide and hydrocarbons to the atmosphere. 

(3) Certain plants e.g., Pinus, Juniparus, Quercus, Pyrus and Vitis metabolise nitrogen oxide and hence their plantation could help in this.

Ans: The organic solvents like- benzene, carbon tetrachloride , toluene etc., are highly toxic in nature. Everyone needs to be careful while using them. For bleaching the cloth hydrogen peroxide is used which is not harmful. Earlier chlorine was used for bleaching the clothes.

Ans: The synthetic detergents are found to be non-biodegradable and hence their use in daily life is to be avoided. Good quality soaps need to be prepared from vegetable oil as they are biodegradable in nature.

Ans: In place of petrol and diesel, the use of CNG and LPG should be preferred as they are pollution free fuels. The other sources such as hydrogen, ethanol etc. can also be used in place of petrol and diesel.

Q47Written answer

Green plants use carbon dioxide for photosynthesis and return oxygen to the atmosphere, even then carbon dioxide is considered to be responsible for greenhouse effect. Explain why? 

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Worked solution

Ans: \[\text{C}{{\text{O}}_{\text{2}}}\]gas is confined to the troposphere only and it forms nearly 0.03 per cent by volume of the atmosphere. With the increased use of fossil fuels, a large amount of carbon dioxide gets released into the atmosphere. Excess of carbon dioxide in the air is removed by the green plants and this maintains an appropriate level of it in the atmosphere. Green plants require carbon dioxide for the process of photosynthesis and  which in turn emits oxygen, thus maintaining the balance in nature. Deforestation and the burning of fossil fuels increase the level of carbon dioxide, and this disturbs the balance in the atmosphere. The increased amount of carbon dioxide in the air is mainly responsible for global warming. 

Q48Written answer

Explain how greenhouse effect causes global warming. 

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Worked solution

Ans: Since the earth’s surface is heated by the sunlight, it radiates a part of this energy back to the space as longer Infrared wavelengths and some of the heat gets trapped by CFCs and water vapours present in the atmosphere. They absorb IR radiations and block a large portion of earth’s emitted radiations. This radiation, absorbed, is partly remitted to the earth’s surface. Therefore, the earth’s surface gets heated up by the phenomenon called greenhouse effect.  Thus, the greenhouse effect is defined as the heating up of the earth’s surface due to trapping of infrared radiations reflected by the earth's surface by the carbon dioxide layer in the atmosphere. So, the heating up of the earth through the greenhouse effect is called global warming. 

Q49Written answer

A farmer was using pesticides on his farm. He used the produce of his farm as food for rearing fishes. He was told that fishes were not fit for human consumption because a large number of pesticides had accumulated in the tissues of fishes. Explain how did this happen? 

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Worked solution

Ans: Pesticides can be defined as the synthetic toxic chemicals  which are meant to kill pests. Most of the organic toxins are water insoluble and non- biodegradable in nature. These high persistent toxins are transferred from lower trophic level to the higher trophic level through the food chain. Over time, the concentration of toxins in higher animals reaches a level which merely causes serious metabolic and physiological disorders. 

Q50Written answer

For dry cleaning, in the place of tetrachloroethane, liquefied carbon dioxide with suitable detergent is an alternative solvent. What type of harm to the environment will be prevented by stopping use of tetrachloroethane? Will use of liquefied carbon dioxide with detergent be completely safe from the point of view of pollution? Explain. 

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Worked solution

Ans: Tetrachloroethene \[\left( \text{C}{{\text{l}}_{\text{2}}}\text{C=CC}{{\text{l}}_{\text{2}}}\text{ } \right)\]was earlier used as solvent for dry cleaning. This compound contaminates the groundwater and is also suspected carcinogen. The process using this compound is now being replaced by a process where liquefied \[\text{C}{{\text{O}}_{\text{2}}}\] is used. Replacement of halogenated solvent by liquid carbon dioxide will result in less harm to the groundwater. These days, hydrogen peroxide is used for the purpose of bleaching clothes in the process of laundry, which gives better results and makes use of a lesser amount of water.


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