Dilution processes of different aqueous solutions, with water, are given in
LIST - I. The effects of dilution of the solutions on \(\left[ {{H^ + }} \right]\) are given in
LIST - II
(Note: Degree of dissociation (a) of weak acid and weak base is \(<<1;\) degree of hydrolysis of salt \(<<1;\) \(\left[ {{H^ + }} \right]\) represents the concentration of \({H^ + }\) ions)
|
LIST-I |
|
LIST-II |
| P. |
(10 mL of 0.1 M NaOH + 20 mL of
0.1 M acetic acid) diluted to 60 mL |
1. |
the value of [H+] does not change
on dilution |
| Q. |
(20 mL of 0.1 M NaOH + 20 mL of
0.1 M acetic acid) diluted to 80 mL |
2. |
the value of [H+] changes to half
of its initial value on dilution |
| R. |
(20 mL of 0.1 M HCL + 20 mL of
0.1 M ammonia solution) diluted to
80 mL |
3. |
the value of [H+] changes to two
times of its initial value on dilution |
| S. |
10 mL saturated solution of Ni(OH)2
in equilibrium with excess solid
Ni(OH)2 is diluted to 20 mL (solid
Ni(OH)2 is still present after dilution). |
4. |
the value of [H+] changes to \({1 \over {\sqrt 2 }}\)
times of its initial value on dilution |
|
|
5. |
the value of [H+] changes to \(\sqrt 2\)
times of its initial value on dilution |
Match each process given in
LIST-I with one or more effect(s) in
LIST-II. The correct option is :
