JEE MAIN 2026 ONLINE 21ST JANUARY MORNING SHIFT

10 mole of oxygen is heated at constant volume from $30^{\circ} \mathrm{C}$ to $40^{\circ} \mathrm{C}$. The change in the internal energy of the gas is $\_\_\_\_$ cal. (The molecular specific heat of oxygen at constant pressure, $C_P=7 \mathrm{cal} / \mathrm{mol} .{ }^{\circ} \mathrm{C}$ and $\left.\mathrm{R}=2 \mathrm{cal} . / \mathrm{mol} .{ }^{\circ} \mathrm{C}.\right)$

Pre-exponential factors of two different reactions of same order are identical. Let activation energy of first reaction exceeds the activation energy of second reaction by $20 \mathrm{~kJ} \mathrm{~mol}^{-1}$. If $\mathrm{k}_1$ and $\mathrm{k}_2$ are the rate constants of first and second reaction respectively at 300 K , then $\ln \frac{\mathrm{k}_2}{\mathrm{k}_1}$ will be $\_\_\_\_$ . (nearest integer) $\left[\mathrm{R}=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right]$

Let $a_1=1$ and for $n \geqslant 1, a_{n+1}=\frac{1}{2} a_n+\frac{n^2-2 n-1}{n^2(n+1)^2}$. Then $\left|\sum_{n=1}^{\infty}\left(a_n-\frac{2}{n^2}\right)\right|$ is equal to $\_\_\_\_$ .

The heat generated in 1 minute between points $A$ and $B$ in the given circuit, when a battery of 9 V with internal resistance of $1 \Omega$ is connected across these points is $\_\_\_\_$ J.

$$\begin{aligned} &\text { Use the following data : }\\ &\begin{array}{|c|c|c|} \hline \text { Substance } & \frac{\Delta_f \mathrm{H}^{\ominus}(500 \mathrm{~K})}{\mathrm{kJ} \mathrm{~mol}^{-1}} & \frac{\mathrm{~S}^{\ominus}(500 \mathrm{~K})}{\mathrm{JK}^{-1} \mathrm{~mol}^{-1}} \\ \hline \mathrm{AB}(\mathrm{~g}) & 32 & 222 \\ \hline \mathrm{~A}_2(\mathrm{~g}) & 6 & 146 \\ \hline \mathrm{~B}_2(\mathrm{~g}) & x & 280 \\ \hline \end{array} \end{aligned}$$

One mole each of $\mathrm{A}_2(\mathrm{~g})$ and $\mathrm{B}_2(\mathrm{~g})$ are taken in a 1 L closed flask and allowed to establish the equilibrium at 500 K .

$$\mathrm{A}_2(\mathrm{~g})+\mathrm{B}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{AB}(\mathrm{~g})$$

The value of $x\left(\mathrm{in} \mathrm{kJ} \mathrm{mol}^{-1}\right)$ is $\_\_\_\_$ . (Nearest integer)

(Given : $\log \mathrm{K}=2.2 \quad \mathrm{R}=8.3 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ )

Let $S=\{(m, n): m, n \in\{1,2,3, \ldots . ., 50\}\}$. If the number of elements $(m, n)$ in $S$ such that $6^m+9^n$ is a multiple of 5 is $p$ and the number of elements ( $m, n$ ) in $S$ such that $m+n$ is a square of a prime number is q , then $\mathrm{p}+\mathrm{q}$ is equal to $\_\_\_\_$ .