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Identify the structure of the final product (D) in the following sequence of the reactions :

Total number of $\mathrm{sp}^2$ hybridised carbon atoms in product D is ____________.

For $\mathrm{t}>-1$, let $\alpha_{\mathrm{t}}$ and $\beta_{\mathrm{t}}$ be the roots of the equation
$$\left((\mathrm{t}+2)^{1 / 7}-1\right) x^2+\left((\mathrm{t}+2)^{1 / 6}-1\right) x+\left((\mathrm{t}+2)^{1 / 21}-1\right)=0 \text {. If } \lim \limits_{\mathrm{t} \rightarrow-1^{+}} \alpha_{\mathrm{t}}=\mathrm{a} \text { and } \lim \limits_{\mathrm{t} \rightarrow-1^{+}} \beta_{\mathrm{t}}=\mathrm{b} \text {, }$$
then $72(a+b)^2$ is equal to ___________.
Butane reacts with oxygen to produce carbon dioxide and water following the equation given below.
$$\mathrm{C}_4 \mathrm{H}_{10}(\mathrm{~g})+\frac{13}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow 4 \mathrm{CO}_2(\mathrm{~g})+5 \mathrm{H}_2 \mathrm{O}(\mathrm{l})$$
If 174.0 kg of butane is mixed with 320.0 kg of $\mathrm{O}_2$, the volume of water formed in liters is
_____________. (Nearest integer)
[Given : (a) Molar mass of C, H, O are $12,1,16 \mathrm{~g} \mathrm{~mol}^{-1}$ respectively, (b) Density of water $\left.=1 \mathrm{~g} \mathrm{~mL}^{-1}\right]$