JEE MAIN 2023 ONLINE 13TH APRIL EVENING SHIFT

Identify the correct order of standard enthalpy of formation of sodium halides :

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : The binding energy per nucleon is practically independent of the atomic number for nuclei of mass number in the range 30 to 170 .

Reason R : Nuclear force is short ranged.

In the light of the above statements, choose the correct answer from the options given below

The correct group of halide ions which can be oxidised by oxygen in acidic medium is :

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : The diameter of colloidal particles in solution should not be much smaller than wavelength of light to show Tyndall effect.

Reason R : The light scatters in all directions when the size of particles is large enough.

In the light of the above statements, choose the correct answer from the options given below:

Better method for preparation of $$\mathrm{BeF}_{2}$$, among the following is :

Given below are two statements related to Ellingham diagram:

Statement I : Ellingham diagrams can be constructed for formation of oxides, sulfides and halides of metals.

Statement II : It consists of plots of $$\Delta_{\mathrm{f}} \mathrm{H}^{0}$$ vs $$\mathrm{T}$$ for formation of oxides of elements.

In the light of the above statements, choose the most appropriate answer from the options given below:

Which of the following are the Green house gases?

A. Water vapour

B. Ozone

C. I$$_2$$

D. Molecular hydrogen

Choose the most appropriate answer from the options given below :

Let for $$A = \left[ {\matrix{ 1 & 2 & 3 \cr \alpha & 3 & 1 \cr 1 & 1 & 2 \cr } } \right],|A| = 2$$. If $$\mathrm{|2\,adj\,(2\,adj\,(2A))| = {32^n}}$$, then $$3n + \alpha $$ is equal to

The random variable $$\mathrm{X}$$ follows binomial distribution $$\mathrm{B}(\mathrm{n}, \mathrm{p})$$, for which the difference of the mean and the variance is 1 . If $$2 \mathrm{P}(\mathrm{X}=2)=3 \mathrm{P}(\mathrm{X}=1)$$, then $$n^{2} \mathrm{P}(\mathrm{X}>1)$$ is equal to :

The plane, passing through the points $$(0,-1,2)$$ and $$(-1,2,1)$$ and parallel to the line passing through $$(5,1,-7)$$ and $$(1,-1,-1)$$, also passes through the point :

Match List I with List II

Choose the correct answer from the options given below:

Let $$\mathrm{N}$$ be the foot of perpendicular from the point $$\mathrm{P}(1,-2,3)$$ on the line passing through the points $$(4,5,8)$$ and $$(1,-7,5)$$. Then the distance of $$N$$ from the plane $$2 x-2 y+z+5=0$$ is :

Let the centre of a circle C be $$(\alpha, \beta)$$ and its radius $$r < 8$$. Let $$3 x+4 y=24$$ and $$3 x-4 y=32$$ be two tangents and $$4 x+3 y=1$$ be a normal to C. Then $$(\alpha-\beta+r)$$ is equal to :

The statement $$(p \wedge(\sim q)) \vee((\sim p) \wedge q) \vee((\sim p) \wedge(\sim q))$$ is equivalent to _________.

To radiate EM signal of wavelength $$\lambda$$ with high efficiency, the antennas should have a minimum size equal to:

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Isotopes of hydrogen have almost same chemical properties, but difference in their rates of reaction.

Reason R : Isotopes of hydrogen have different enthalpy of bond dissociation.

In the light of the above statements, choose the most appropriate answer from the options given below:

If the formula of Borax is $$\mathrm{Na_2B_4O_x(OH)_y~.~zH_2O}$$, then $$x+y+z=$$ ___________

Sodium metal crystallizes in a body centred cubic lattice with unit cell edge length of $$4~\mathop A\limits^o $$. The radius of sodium atom is __________ $$\times ~10^{-1}$$ $$\mathop A\limits^o $$ (Nearest integer)

A bi convex lens of focal length $$10 \mathrm{~cm}$$ is cut in two identical parts along a plane perpendicular to the principal axis. The power of each lens after cut is ____________ D.

A car accelerates from rest to $$u \mathrm{~m} / \mathrm{s}$$. The energy spent in this process is E J. The energy required to accelerate the car from $$u \mathrm{~m} / \mathrm{s}$$ to $$2 \mathrm{u} \mathrm{m} / \mathrm{s}$$ is $$\mathrm{nE~J}$$. The value of $$\mathrm{n}$$ is ____________.

A light rope is wound around a hollow cylinder of mass 5 kg and radius 70 cm. The rope is pulled with a force of 52.5 N. The angular acceleration of the cylinder will be _________ rad s$$^{-2}$$.

A straight wire $$\mathrm{AB}$$ of mass $$40 \mathrm{~g}$$ and length $$50 \mathrm{~cm}$$ is suspended by a pair of flexible leads in uniform magnetic field of magnitude $$0.40 \mathrm{~T}$$ as shown in the figure. The magnitude of the current required in the wire to remove the tension in the supporting leads is ___________ A.

$$\left(\right.$$ Take $$g=10 \mathrm{~ms}^{-2}$$ ).

Two plates $$\mathrm{A}$$ and $$\mathrm{B}$$ have thermal conductivities $$84 ~\mathrm{Wm}^{-1} \mathrm{~K}^{-1}$$ and $$126 ~\mathrm{Wm}^{-1} \mathrm{~K}^{-1}$$ respectively. They have same surface area and same thickness. They are placed in contact along their surfaces. If the temperatures of the outer surfaces of $$\mathrm{A}$$ and $$\mathrm{B}$$ are kept at $$100^{\circ} \mathrm{C}$$ and $$0{ }^{\circ} \mathrm{C}$$ respectively, then the temperature of the surface of contact in steady state is _____________ $${ }^{\circ} \mathrm{C}$$.

The foci of a hyperbola are $$( \pm 2,0)$$ and its eccentricity is $$\frac{3}{2}$$. A tangent, perpendicular to the line $$2 x+3 y=6$$, is drawn at a point in the first quadrant on the hyperbola. If the intercepts made by the tangent on the $$\mathrm{x}$$ - and $$\mathrm{y}$$-axes are $$\mathrm{a}$$ and $$\mathrm{b}$$ respectively, then $$|6 a|+|5 b|$$ is equal to __________

$$1 \mathrm{~g}$$ of a carbonate $$\left(\mathrm{M}_{2} \mathrm{CO}_{3}\right)$$ on treatment with excess $$\mathrm{HCl}$$ produces $$0.01 \mathrm{~mol}$$ of $$\mathrm{CO}_{2}$$. The molar mass of $$\mathrm{M}_{2} \mathrm{CO}_{3}$$ is __________ $$\mathrm{g} ~\mathrm{mol}^{-1}$$. (Nearest integer)

In the circuit shown, the energy stored in the capacitor is $$n ~\mu \mathrm{J}$$. The value of $$n$$ is __________

An insulated copper wire of 100 turns is wrapped around a wooden cylindrical core of the cross-sectional area $$24 \mathrm{~cm}^{2}$$. The two ends of the wire are connected to a resistor. The total resistance in the circuit is $$12 ~\Omega$$. If an externally applied uniform magnetic field in the core along its axis changes from $$1.5 \mathrm{~T}$$ in one direction to $$1.5 ~\mathrm{T}$$ in the opposite direction, the charge flowing through a point in the circuit during the change of magnetic field will be ___________ $$\mathrm{mC}$$.

In an experiment with sonometer when a mass of $$180 \mathrm{~g}$$ is attached to the string, it vibrates with fundamental frequency of $$30 \mathrm{~Hz}$$. When a mass $$\mathrm{m}$$ is attached, the string vibrates with fundamental frequency of $$50 \mathrm{~Hz}$$. The value of $$\mathrm{m}$$ is ___________ g.

Three point charges $$\mathrm{q},-2 \mathrm{q}$$ and $$2 \mathrm{q}$$ are placed on $x$-axis at a distance $$x=0, x=\frac{3}{4} R$$ and $$x=R$$ respectively from origin as shown. If $$\mathrm{q}=2 \times 10^{-6} \mathrm{C}$$ and $$\mathrm{R}=2 \mathrm{~cm}$$, the magnitude of net force experienced by the charge $$-2 q$$ is ___________ N.

An atom absorbs a photon of wavelength $$500 \mathrm{~nm}$$ and emits another photon of wavelength $$600 \mathrm{~nm}$$. The net energy absorbed by the atom in this process is $$n \times 10^{-4} ~\mathrm{eV}$$. The value of n is __________. [Assume the atom to be stationary during the absorption and emission process] (Take $$\mathrm{h}=6.6 \times 10^{-34} ~\mathrm{Js}$$ and $$\mathrm{c}=3 \times 10^{8} \mathrm{~m} / \mathrm{s}$$ )

Sea water contains $$29.25 \% ~\mathrm{NaCl}$$ and $$19 \% ~\mathrm{MgCl}_{2}$$ by weight of solution. The normal boiling point of the sea water is _____________ $${ }^{\circ} \mathrm{C}$$ (Nearest integer)

Assume $$100 \%$$ ionization for both $$\mathrm{NaCl}$$ and $$\mathrm{MgCl}_{2}$$

Given : $$\mathrm{K}_{\mathrm{b}}\left(\mathrm{H}_{2} \mathrm{O}\right)=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$

Molar mass of $$\mathrm{NaCl}$$ and $$\mathrm{MgCl}_{2}$$ is 58.5 and 95 $$\mathrm{g} \mathrm{~mol}^{-1}$$ respectively.

20 mL of $$0.1 ~\mathrm{M} ~\mathrm{NaOH}$$ is added to $$50 \mathrm{~mL}$$ of $$0.1 ~\mathrm{M}$$ acetic acid solution. The $$\mathrm{pH}$$ of the resulting solution is ___________ $$\times 10^{-2}$$ (Nearest integer)

Given : $$\mathrm{pKa}\left(\mathrm{CH}_{3} \mathrm{COOH}\right)=4.76$$

$$\log 2=0.30$$

$$\log 3=0.48$$

See the following chemical reaction:

$$\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}+\mathrm{XH}^{+}+6 \mathrm{~F}_{e}^{2+} \rightarrow \mathrm{YCr}^{3+}+6 \mathrm{~F}_{e}^{3+}+\mathrm{Z} \mathrm{H}_{2} \mathrm{O}$$

The sum of $$\mathrm{X}, \mathrm{Y}$$ and $$\mathrm{Z}$$ is ___________

At $$298 \mathrm{~K}$$, the standard reduction potential for $$\mathrm{Cu}^{2+} / \mathrm{Cu}$$ electrode is $$0.34 \mathrm{~V}$$.

Given : $$\mathrm{K}_{\mathrm{sp}} \mathrm{Cu}(\mathrm{OH})_{2}=1 \times 10^{-20}$$

Take $$\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \mathrm{~V}$$

The reduction potential at $$\mathrm{pH}=14$$ for the above couple is $$(-) x \times 10^{-2} \mathrm{~V}$$. The value of $$x$$ is ___________

A(g) $$\to$$ 2B(g) + C(g) is a first order reaction. The initial pressure of the system was found to be 800 mm Hg which increased to 1600 mm Hg after 10 min. The total pressure of the system after 30 min will be _________ mm Hg. (Nearest integer)

The orbital angular momentum of an electron in $$3 \mathrm{~s}$$ orbital is $$\frac{x h}{2 \pi}$$. The value of $$x$$ is ____________ (nearest integer)

The mean and standard deviation of the marks of 10 students were found to be 50 and 12 respectively. Later, it was observed that two marks 20 and 25 were wrongly read as 45 and 50 respectively. Then the correct variance is _________

$$0.400 \mathrm{~g}$$ of an organic compound $$(\mathrm{X})$$ gave $$0.376 \mathrm{~g}$$ of $$\mathrm{AgBr}$$ in Carius method for estimation of bromine. $$\%$$ of bromine in the compound $$(\mathrm{X})$$ is ___________.

(Given: Molar mass $$\mathrm{AgBr=188~g~mol^{-1}}$$

$$\mathrm{Br}=80 \mathrm{~g} \mathrm{~mol}^{-1}$$)

Let $$\mathrm{A}=\{-4,-3,-2,0,1,3,4\}$$ and $$\mathrm{R}=\left\{(a, b) \in \mathrm{A} \times \mathrm{A}: b=|a|\right.$$ or $$\left.b^{2}=a+1\right\}$$ be a relation on $$\mathrm{A}$$. Then the minimum number of elements, that must be added to the relation $$\mathrm{R}$$ so that it becomes reflexive and symmetric, is __________

The remainder, when $$7^{103}$$ is divided by 17, is __________

Total numbers of 3-digit numbers that are divisible by 6 and can be formed by using the digits $$1,2,3,4,5$$ with repetition, is _________.

Let $$[\alpha]$$ denote the greatest integer $$\leq \alpha$$. Then $$[\sqrt{1}]+[\sqrt{2}]+[\sqrt{3}]+\ldots+[\sqrt{120}]$$ is equal to __________

In the equation $$\left[X+\frac{a}{Y^{2}}\right][Y-b]=\mathrm{R} T, X$$ is pressure, $$Y$$ is volume, $$\mathrm{R}$$ is universal gas constant and $$T$$ is temperature. The physical quantity equivalent to the ratio $$\frac{a}{b}$$ is:

Let $$f(x)=\sum_\limits{k=1}^{10} k x^{k}, x \in \mathbb{R}$$. If $$2 f(2)+f^{\prime}(2)=119(2)^{\mathrm{n}}+1$$ then $$\mathrm{n}$$ is equal to ___________

Let $$f_{n}=\int_\limits{0}^{\frac{\pi}{2}}\left(\sum_\limits{k=1}^{n} \sin ^{k-1} x\right)\left(\sum_\limits{k=1}^{n}(2 k-1) \sin ^{k-1} x\right) \cos x d x, n \in \mathbb{N}$$. Then $$f_{21}-f_{20}$$ is equal to _________

If $$y=y(x)$$ is the solution of the differential equation

$$\frac{d y}{d x}+\frac{4 x}{\left(x^{2}-1\right)} y=\frac{x+2}{\left(x^{2}-1\right)^{\frac{5}{2}}}, x > 1$$ such that

$$y(2)=\frac{2}{9} \log _{e}(2+\sqrt{3}) \text { and } y(\sqrt{2})=\alpha \log _{e}(\sqrt{\alpha}+\beta)+\beta-\sqrt{\gamma}, \alpha, \beta, \gamma \in \mathbb{N} \text {, then } \alpha \beta \gamma \text { is equal to }$$ :

The distance travelled by an object in time $$t$$ is given by $$s=(2.5) t^{2}$$. The instantaneous speed of the object at $$\mathrm{t}=5 \mathrm{~s}$$ will be:

For $$x \in(-1,1]$$, the number of solutions of the equation $$\sin ^{-1} x=2 \tan ^{-1} x$$ is equal to __________.

The mean free path of molecules of a certain gas at STP is $$1500 \mathrm{~d}$$, where $$\mathrm{d}$$ is the diameter of the gas molecules. While maintaining the standard pressure, the mean free path of the molecules at $$373 \mathrm{~K}$$ is approximately:

A passenger sitting in a train A moving at $$90 \mathrm{~km} / \mathrm{h}$$ observes another train $$\mathrm{B}$$ moving in the opposite direction for $$8 \mathrm{~s}$$. If the velocity of the train B is $$54 \mathrm{~km} / \mathrm{h}$$, then length of train B is:

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : A spherical body of radius $$(5 \pm 0.1) \mathrm{mm}$$ having a particular density is falling through a liquid of constant density. The percentage error in the calculation of its terminal velocity is $$4 \%$$.

Reason R : The terminal velocity of the spherical body falling through the liquid is inversely proportional to its radius.

In the light of the above statements, choose the correct answer from the options given below

A particle executes SHM of amplitude A. The distance from the mean position when its's kinetic energy becomes equal to its potential energy is :

The initial pressure and volume of an ideal gas are P$$_0$$ and V$$_0$$. The final pressure of the gas when the gas is suddenly compressed to volume $$\frac{V_0}{4}$$ will be :

(Given $$\gamma$$ = ratio of specific heats at constant pressure and at constant volume)

A vehicle of mass $$200 \mathrm{~kg}$$ is moving along a levelled curved road of radius $$70 \mathrm{~m}$$ with angular velocity of $$0.2 ~\mathrm{rad} / \mathrm{s}$$. The centripetal force acting on the vehicle is:

In the network shown below, the charge accumulated in the capacitor in steady state will be:

An electron is moving along the positive $$\mathrm{x}$$-axis. If the uniform magnetic field is applied parallel to the negative z-axis, then

A. The electron will experience magnetic force along positive y-axis

B. The electron will experience magnetic force along negative y-axis

C. The electron will not experience any force in magnetic field

D. The electron will continue to move along the positive $$\mathrm{x}$$-axis

E. The electron will move along circular path in magnetic field

Choose the correct answer from the options given below:

Given below are two statements:

Statement I : An AC circuit undergoes electrical resonance if it contains either a capacitor or an inductor.

Statement II : An AC circuit containing a pure capacitor or a pure inductor consumes high power due to its non-zero power factor.

In the light of above statements, choose the correct answer form the options given below:

A $$10 ~\mu \mathrm{C}$$ charge is divided into two parts and placed at $$1 \mathrm{~cm}$$ distance so that the repulsive force between them is maximum. The charges of the two parts are:

Given below are two statements:

Statement I : For a planet, if the ratio of mass of the planet to its radius increases, the escape velocity from the planet also increases.

Statement II : Escape velocity is independent of the radius of the planet.

In the light of above statements, choose the most appropriate answer form the options given below

Two planets A and B of radii $$\mathrm{R}$$ and 1.5 R have densities $$\rho$$ and $$\rho / 2$$ respectively. The ratio of acceleration due to gravity at the surface of $$\mathrm{B}$$ to $$\mathrm{A}$$ is:

Given below are two statements :

Statement I : $$\mathrm{SO}_{2}$$ and $$\mathrm{H}_{2} \mathrm{O}$$ both possess V-shaped structure.

Statement II : The bond angle of $$\mathrm{SO}_{2}$$ is less than that of $$\mathrm{H}_{2} \mathrm{O}$$.

In the light of the above statements, choose the most appropriate answer from the options given below:

In an electromagnetic wave, at an instant and at particular position, the electric field is along the negative $$z$$-axis and magnetic field is along the positive $$x$$-axis. Then the direction of propagation of electromagnetic wave is:

In a Young's double slits experiment, the ratio of amplitude of light coming from slits is $$2: 1$$. The ratio of the maximum to minimum intensity in the interference pattern is:

The output from NAND gate having inputs A and B given below will be,

What happens when methane undergoes combustion in systems A and B respectively?

Given below are two statements:

Statement I : Out of microwaves, infrared rays and ultraviolet rays, ultraviolet rays are the most effective for the emission of electrons from a metallic surface.

Statement II : Above the threshold frequency, the maximum kinetic energy of photoelectrons is inversely proportional to the frequency of the incident light.

In the light of above statements, choose the correct answer form the options given below

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Order of acidic nature of the following compounds is A > B > C.

Reason R : Fluoro is a stronger electron withdrawing group than Chloro group.

In the light of the above statements, choose the correct answer from the options given below:

The total number of stereoisomers for the complex $$\left[\mathrm{Cr}(o x)_{2} \mathrm{ClBr}\right]^{3-}$$ (where $$o x=$$ oxalate) is :

Which of the following complexes will exhibit maximum attraction to an applied magnetic field?

In the wet tests for detection of various cations by precipitation, $$\mathrm{Ba}^{2+}$$ cations are detected by obtaining precipitate of

Given below are two statements :

Statement I : Tropolone is an aromatic compound and has $$8 \pi$$ electrons.

Statement II : $$\pi$$ electrons of $$ > \mathrm{C}=\mathrm{O}$$ group in tropolone is involved in aromaticity.

In the light of the above statements, choose the correct answer from the options given below:

The covalency and oxidation state respectively of boron in $$\left[\mathrm{BF}_{4}\right]^{-}$$, are :

The naturally occurring amino acid that contains only one basic functional group in its chemical structure is

The major product for the following reaction is:

Match List I with List II

1 - Bromopropane is reacted with reagents in List I to give product in List II

Choose the correct answer from the options given below:

Compound $$\mathrm{A}$$ from the following reaction sequence is:

Let $$\alpha, \beta$$ be the roots of the equation $$x^{2}-\sqrt{2} x+2=0$$. Then $$\alpha^{14}+\beta^{14}$$ is equal to

Let a$$_1$$, a$$_2$$, a$$_3$$, .... be a G.P. of increasing positive numbers. Let the sum of its 6^th and 8^th terms be 2 and the product of its 3^rd and 5^th terms be $$\frac{1}{9}$$. Then $$6(a_2+a_4)(a_4+a_6)$$ is equal to

Let $$|\vec{a}|=2,|\vec{b}|=3$$ and the angle between the vectors $$\vec{a}$$ and $$\vec{b}$$ be $$\frac{\pi}{4}$$. Then $$|(\vec{a}+2 \vec{b}) \times(2 \vec{a}-3 \vec{b})|^{2}$$ is equal to :

Let $$S=\left\{z \in \mathbb{C}: \bar{z}=i\left(z^{2}+\operatorname{Re}(\bar{z})\right)\right\}$$. Then $$\sum_\limits{z \in \mathrm{S}}|z|^{2}$$ is equal to :

The coefficient of $$x^{5}$$ in the expansion of $$\left(2 x^{3}-\frac{1}{3 x^{2}}\right)^{5}$$ is :

All words, with or without meaning, are made using all the letters of the word MONDAY. These words are written as in a dictionary with serial numbers. The serial number of the word MONDAY is :

The line, that is coplanar to the line $$\frac{x+3}{-3}=\frac{y-1}{1}=\frac{z-5}{5}$$, is :

Let for a triangle $$\mathrm{ABC}$$,

$$\overrightarrow{\mathrm{AB}}=-2 \hat{i}+\hat{j}+3 \hat{k}$$

$$\overrightarrow{\mathrm{CB}}=\alpha \hat{i}+\beta \hat{j}+\gamma \hat{k}$$

$$\overrightarrow{\mathrm{CA}}=4 \hat{i}+3 \hat{j}+\delta \hat{k}$$

If $$\delta > 0$$ and the area of the triangle $$\mathrm{ABC}$$ is $$5 \sqrt{6}$$, then $$\overrightarrow{C B} \cdot \overrightarrow{C A}$$ is equal to

Let $$(\alpha, \beta)$$ be the centroid of the triangle formed by the lines $$15 x-y=82,6 x-5 y=-4$$ and $$9 x+4 y=17$$. Then $$\alpha+2 \beta$$ and $$2 \alpha-\beta$$ are the roots of the equation :

The range of $$f(x)=4 \sin ^{-1}\left(\frac{x^{2}}{x^{2}+1}\right)$$ is

If the system of equations

$$2 x+y-z=5$$

$$2 x-5 y+\lambda z=\mu$$

$$x+2 y-5 z=7$$

has infinitely many solutions, then $$(\lambda+\mu)^{2}+(\lambda-\mu)^{2}$$ is equal to

If $$\lim_\limits{x \rightarrow 0} \frac{e^{a x}-\cos (b x)-\frac{cx e^{-c x}}{2}}{1-\cos (2 x)}=17$$, then $$5 a^{2}+b^{2}$$ is equal to

The area of the region $$\left\{(x, y): x^{2} \leq y \leq\left|x^{2}-4\right|, y \geq 1\right\}$$ is

The value of $${{{e^{ - {\pi \over 4}}} + \int\limits_0^{{\pi \over 4}} {{e^{ - x}}{{\tan }^{50}}xdx} } \over {\int\limits_0^{{\pi \over 4}} {{e^{ - x}}({{\tan }^{49}}x + {{\tan }^{51}}x)dx} }}$$ is