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NCERT Exemplar · Class 11 · Chemistry

Chapter 1: Some Basic Concepts of Chemistry

Practice each question, then open the answer or worked solution.

Questions

45 questions
Q21Multiple choice

Which of the following terms is unitless?

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Correct option: C
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Worked solution

Option (iii) and (iv) are the answers.

Q22Written answer

One of the statements of Dalton’s atomic theory is given below:

“Compounds are formed when atoms of different elements combine in a fixed

ratio”

Which of the following laws is not related to this statement?

(i) Law of conservation of mass

(ii) Law of definite proportions

(iii) Law of multiple proportions

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Worked solution

Option (i) and (iv)

III. Short Answer Type

Q23Written answer

What will be the mass of one atom of C-12 in grams?

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Worked solution

1 mole of carbon atom = 12g= 6.022 × 1023 atoms.

Q24Written answer

How many significant figures should be present in the answer to the following

calculations?

2.5 1.25 3.5/2.01

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Worked solution

Two significant figures should be present in this.

Since the least number of significant figures from the given figure is 2 (in 2.5 and 3.5).

Q25Written answer

What is the symbol for the SI unit of a mole? How is the mole defined?

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Worked solution

The symbol for the SI unit of the mole is mol. A mole is defined as the amount of substance that contains as many entities as there are atoms in 12g carbon.

Q26Written answer

What is the difference between molality and molarity?

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Worked solution

Molarity is the number of moles of solute dissolved in 1 litre of the solution. Molality is the number of moles of solute present in 1kg of the solvent.

Q27Written answer

Calculate the mass percent of calcium, phosphorus and oxygen in calcium

phosphate Ca3(PO4)

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Worked solution

Molecular mass of Ca3(PO4) = 3*40+2*31+8*16 =310

Mass per cent of Ca = 3*40/310*100 = 38.71%

Mass per cent of P = 2*31/310*100 = 20%

Mass per cent of O = 8*16/310 = 41.29%

Q28Written answer

45.4 L of dinitrogen reacted with 22.7 L of dioxygen and 45.4 L of nitrous

oxide was formed. The reaction is given below:

2N2(g) + O2(g) → 2N2O(g)

Which law is being obeyed in this experiment? Write the statement of the law?

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Worked solution

The above experiment proves Gay-Lussac’s law which states that gases combine or produced in a chemical reaction in a simple whole-number ratio by volume provided that all gases are the same temperature and pressure.

Q29Written answer

If two elements can combine to form more than one compound, the masses of

one element that combine with a fixed mass of the other element, are in whole-number ratio.

(a) Is this statement true?

(b) If yes, according to which law?

(c) Give one example related to this law.

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Worked solution

(a) Yes, the statement is true.

(b) According to the law of multiple proportions

(c), Hydrogen and oxygen react to form water and hydrogen peroxide

H2 + 1/2O2 → H2O

H2 + O2 → H2O2

Masses of oxygen which combine the fixed mass of hydrogen are in the ratio 16:32 or 1

Q30Written answer

Calculate the average atomic mass of hydrogen using the following data :

Isotope % Natural abundance Molar mass
1H 99.985 1
2H 0.015 2
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Worked solution

Average atomic mass = 99.985*1+0.015*2/100

=099.985*1+0.015*2/100

=1.00015u