The following values are given in the question:
Number of silicon atoms, N = 5 × 10 28 atoms/m3
Number of arsenic atoms, nAS =5×1022atoms/m3
Number of indium atoms, nIn=5×1022atoms/m3
ni=1.5×1016electrons/m3
ne=5×1022−1.5×1016=4.99×1022
Let us consider the number of holes to be nh
In the thermal equilibrium, nenh = ni2
Calculating, we get
nh=4.51×109
Here, ne>nh, therefore, the material is an n-type semiconductor.
Q 9: In an intrinsic semiconductor, the energy gap Eg is 1.2eV. Its hole mobility is much smaller than electron mobility and independent of temperature. What is the ratio between conductivity at 600K and that at 300K? Assume that the temperature dependence of intrinsic carrier concentration ni is given by
\(\begin{array}{l}n_{i}=n_{0}exp\left [ -\frac{E_{g}}{2k_{B}T} \right ]\end{array} \)
where n0 is constant.
Energy gap in an intrinsic semiconductor, Eg = 1.2 eV
The temperature dependence of the intrinsic carrier concentration is given as
\(\begin{array}{l}n_{i}=n_{0}exp\left [ -\frac{E_{g}}{2k_{B}T} \right ]\end{array} \)
Here, kB is the Boltzmann constant = 8.62 x 10-5 eV/K
T is the temperature
n0 is a constant
Initial temperature, T1 = 300 K
The intrinsic carrier concentration at the temperature 300 K can be written as
\(\begin{array}{l}n_{i1}=n_{0}exp\left [ -\frac{E_{g}}{2k_{B}\times 300} \right ]\end{array} \)
Final temperature, T2 = 600 K
The intrinsic carrier concentration at the temperature 600 K can be written as
\(\begin{array}{l}n_{i2}=n_{0}exp\left [ -\frac{E_{g}}{2k_{B}\times 600} \right ]\end{array} \)
The ratio between conductivity at 600K and that at 300K is equal to the ratio between the respective carrier concentration at these temperatures.
\(\begin{array}{l}\frac{n_{i2}}{n_{i1}}= \frac{n_{0}exp\left [ -\frac{E_{g}}{2k_{B}\times 600} \right ]}{n_{0}exp\left [ -\frac{E_{g}}{2k_{B}\times 300} \right ]}\end{array} \)
\(\begin{array}{l}= exp \frac{E_{g}}{2k_{B}}\left [ \frac{1}{300}-\frac{1}{600} \right ]\end{array} \)
\(\begin{array}{l}= exp \frac{1.2}{2\times 8.62\times 10^{-5}}\left [ \frac{1}{300}-\frac{1}{600} \right ]\end{array} \)
\(\begin{array}{l}= exp \frac{1.2}{17.24\times 10^{-5}}\left [ \frac{2-1}{600} \right ]\end{array} \)
= exp (11.6) = 1.09 x 105
There, the ratio between the conductivities is 1.09 x 105.