Ionic Equilibrum - Physical Chemistry - Chemistry Previous Year Questions

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The pH of pure water at $80^{\circ} \mathrm{C}$ is

Assertion (A) $\mathrm{p} K_a$ of phenol is 4.19 and that of benzoic acid is 10 .

Reason (R) Phenoxide ion is stabilised by non-equivalent resonance structures whereas benzoate ion by two equivalent resonance structures.

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At 298 K the molar solubility of $\mathrm{Cd}(\mathrm{OH})_2$ in $0.1 \mathrm{M} \mathrm{KOH}_{\mathrm{OH}}$ solution is $x \times 10^{-y}$. The values of $x$ and $y$ are respectively.

(At $298 \mathrm{~K}, K_{s p}$ of $\mathrm{Cd}(\mathrm{OH})_2=2.5 \times 10^{-14}$ )

Which of the following does not form a buffer solution?

Match the given ionisation constant values with the corresponding acids.

$$\begin{array}{lll} \hline \text { A. } & \mathrm{HI} & \text { (i) } 3.2 \times 10^9 \\ \hline \text { B. } & \mathrm{HF} & \text { (ii) } 3.5 \times 10^{-4} \\ \hline \text { C. } & \mathrm{HCl} & \text { (iii) } 1.3 \times 10^6 \\ \hline \text { D. } & \mathrm{HBr} & \text { (iv) } 1.0 \times 10^9 \\ \hline \end{array}$$

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Calculate the molar solubility of calcium hydroxide $\mathrm{Ca}(\mathrm{OH})_2$ in 0.10 M NaOH solution. The ionic product of calcium hydroxide is $5.5 \times 10^{-6}$.

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Ammonia is a Lewis base because it is

How many of the following are diprotic acids? Citric acid, chromic acid, oxalic acid, pyrosulphuric acid, sulphurous acid